1: With (S)-(-)-Indoline-2-carboxylic acid; hydroquinone in dichloromethane; N,N-dimethyl-formamide
T=20°C; asymmetric Diels-Alder reaction; P=6000600 Torr; 20 h;
2: With sodium tetrahydroborate in methanol
optical yield given as percent ee;
(tetramethylammonium)4[(iron)4((C5H4NCHNC6H3SO3)2)6]; oxygen; methylene blue; acetic acid in water
T=25°C; pH=4; 9 h; Irradiation;
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Journal of the American Chemical Society, 2013 , vol. 135, # 51 p. 19143 - 19146
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Journal of the American Chemical Society, 2013 , vol. 135, # 51 p. 19143 - 19146
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