2,5-二甲基-2,5-己二醇合成路线 （共 107 条）
反应条件
die Wasserstoffanlagerung verlaeuft rascher als bei der β-Form; higher-melting 2.5-dimethyl-hexene-(3)-diol-(2.5);
参考文献
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, , vol. 49, p. 133
Chem. Zentralbl., , vol. 94, # III p. 1391
参考文献
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, , vol. 35, p. 882
Chem. Zentralbl., , vol. 75, # I p. 578
Justus Liebigs Annalen der Chemie, , vol. 343, p. 364
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 143, p. 496
参考文献
Chemische Berichte, , vol. 35, p. 2139
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 143, p. 496
反应条件
1: conc. HCl, HCl gas / 0.25 h / 0 °C 2: 81.9 percent / AlCl3 / 24 h / Heating 3: 49.9 percent / HNO3, H2SO4 / 1 h / -10 °C 4: 48 percent / hydrogen / Pd/C / ethanol View Scheme
参考文献
Kagechika, Hiroyuki; Kawachi, Emiko; Hashimoto, Yuichi; Himi, Toshiyuki; Shudo, Koichi
Journal of Medicinal Chemistry, 1988 , vol. 31, # 11 p. 2182 - 2192
反应条件
1: conc. HCl, HCl gas / 0.25 h / 0 °C 2: 81.9 percent / AlCl3 / 24 h / Heating 3: 49.9 percent / HNO3, H2SO4 / 1 h / -10 °C 4: 48 percent / hydrogen / Pd/C / ethanol 5: 86.7 percent / pyridine / benzene / Ambient temperature 6: aq. NaOH / ethanol / Ambient temperature View Scheme
参考文献
Kagechika, Hiroyuki; Kawachi, Emiko; Hashimoto, Yuichi; Himi, Toshiyuki; Shudo, Koichi
Journal of Medicinal Chemistry, 1988 , vol. 31, # 11 p. 2182 - 2192
反应条件
1: conc. HCl, HCl gas / 0.25 h / 0 °C 2: 81.9 percent / AlCl3 / 24 h / Heating 3: 49.9 percent / HNO3, H2SO4 / 1 h / -10 °C 4: 48 percent / hydrogen / Pd/C / ethanol 5: 86.7 percent / pyridine / benzene / Ambient temperature View Scheme
参考文献
Kagechika, Hiroyuki; Kawachi, Emiko; Hashimoto, Yuichi; Himi, Toshiyuki; Shudo, Koichi
Journal of Medicinal Chemistry, 1988 , vol. 31, # 11 p. 2182 - 2192
→
22306-30-51,1,4,4,5,5,8,8-八甲基-1,2,3,4,5,6,7,8-八氢蒽
反应条件
1: HCl 2: AlCl3 View Scheme
参考文献
Bruson; Kroeger
Journal of the American Chemical Society, 1940 , vol. 62, p. 36,43
→
22306-30-51,1,4,4,5,5,8,8-八甲基-1,2,3,4,5,6,7,8-八氢蒽
参考文献
Labanskii; Zukerwanik
Doklady Akademii Nauk SSSR, 1951 , vol. 80, p. 369,371
Chem.Abstr., 1952 , p. 5022
