in benzene-d6 (Ar, Schlenk) a NMR-tube was charged with complex and B(C6F5)3, dissolved in C6D6 at room temp., 5 min to 6 days; detected by NMR spectra;
in toluene under Ar, 0.9 equiv. of B-comp. in PhMe was added to PhMe soln. of Al-compd., several days, then reflux for 24 h; monitored by NMR, no signal in (27)Al spectrum, and an unidentified B-copd. was also observed by (11)B NMR;
参考文献
Knabel, Klaus; Noeth, Heinrich
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2005 , vol. 60, # 10 p. 1027 - 1035
in deuterated toluene byproducts: Al(C6F5)3; using Schlenk techniques; mixing of solns. of B(C6F5)3 and Al2Me6 in toluene-d8 in NMR tube for 10 min, addn. of soln. of ZrMe2(C5Me5)2 in toluene-d8 at 20°C with ratio B(C6F5)3, Al2Me6 and (C5Me5)2ZrMe2 2:1:1; monitoring by NMR;
参考文献
Mathis, Deborah; Couzijn, Erik P. A.; Chen, Peter
Organometallics, 2011 , vol. 30, # 14 p. 3834 - 3843
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反应条件
Inert atmosphere;
参考文献
Yan, Kaking; Duchimaza Heredia, Juan J.; Ellern, Arkady; Gordon, Mark S.; Sadow, Aaron D.
Journal of the American Chemical Society, 2013 , vol. 135, # 40 p. 15225 - 15237
DOW GLOBAL TECHNOLOGIES LLC; WENZEL, Timothy T.; PETERSON, Thomas H.; TIMMERS, Francis J.; FRAZIER, Kevin A.; CLARK, Thomas P.; FROESE, Robert
Patent: WO2014/4954 A1, 2014 ;
Location in patent: Paragraph 019 ;
