1: With C52H60O10P2; hydrogen; dicarbonylacetylacetonato rhodium (I) in toluene T=80°C; P=5175.52 Torr; 1 h; 2: With anhydrous butyl ether in toluene Product distribution / selectivity;
1: With C56H56O10P2; hydrogen; dicarbonylacetylacetonato rhodium (I) in toluene T=80°C; P=5175.52 Torr; 1 h; 2: With anhydrous butyl ether in toluene Product distribution / selectivity;
hydrogen; IrH5(PPh3)2 in trifluoroacetic acid T=70°C; P=91200 Torr; 1.5 h; other solvent, reaction time; Product distribution;
参考文献
Markosyan, S. M.; Kalinkin, M. I.; Parnes, Z. H.; Kursanov, D. N.
Doklady Chemistry, 1980 , vol. 255, p. 533 - 536
Dokl. Akad. Nauk SSSR Ser. Khim., 1980 , vol. 255, # 3 p. 599 - 602
hydrogenchloride in tetrahydrofuran mixing of MnBu2 with Li-salt in THF (molar ratio 1:1.5, -78°C, 1 h), rise of temp. to 25°C (over 1 h); gas liquid chromy. after quenching with 2 N HCl;
参考文献
Negishi, Ei-ichi; Akiyoshi, Kazunari; O'Connor, Brian; Takagi, Kentaro; Wu, Guangzhong
Journal of the American Chemical Society, 1989 , vol. 111, # 8 p. 3089 - 3091
