tert.-butylhydroperoxide; Mn(2+)*C6H10(NCH3CH2C5H4N)2*2CF3SO3(1-)=Mn(C6H10(NCH3CH2C5H4N)2)(CF3SO3)2 in acetonitrile T=0°C; 3.5 h; optical yield given as percent eeenantioselective reaction;
参考文献
Ottenbacher, Roman V.; Bryliakov, Konstantin P.; Talsi, Evgenii P.
Inorganic Chemistry, 2010 , vol. 49, # 18 p. 8620 - 8628
tert.-butylhydroperoxide; MoVIO2(acetylacetone)2 in chlorobenzene T=60°C; 6 h; influence of additional amounts of reactionsproducts on the rate of reaction; KineticsRate constantEquilibrium constant;
参考文献
Megdiche, R.; Schnurpfeil, D.
Journal fuer Praktische Chemie (Leipzig), 1983 , vol. 325, # 1 p. 113 - 122
