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乙二醇
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
庚醛
合成路线
(共 1187 条)
111-71-7
庚醛
+
95-48-7
邻甲酚
→
反应条件
57100-84-2
反应条件
hydrogenchloride
参考文献
Harden; Reid
Journal of the American Chemical Society, 1932 , vol. 54, p. 4325,4327, 4331
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Easson et al.
Quarterly Journal of Pharmacy and Pharmacology, 1934 , vol. 7, p. 509,510, 511
75-15-0
+
111-71-7
庚醛
+
63846-79-7
+
74-88-4
→
反应条件
1133931-99-3
+
57198-98-8
反应条件
1: (tributylstannyl)methyl 2,4,6-triisopropylbenzoate With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.0833333 h; Inert atmosphere; 2: heptanal in tetrahydrofuran; hexane T=-78°C; 0.166667 h; Inert atmosphere; 3: carbon disulfide; methyl iodide Further stages;
参考文献
Kapeller, Dagmar C.; Hammerschmidt, Friedrich
Journal of Organic Chemistry, 2009 , vol. 74, # 6 p. 2380 - 2388
75-15-0
+
111-71-7
庚醛
+
1133931-84-6
+
74-88-4
→
反应条件
反应条件
1: C29H51(2)HO2Sn With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.0833333 h; Inert atmosphere; 2: heptanal in tetrahydrofuran; hexane T=-78°C; 0.166667 h; Inert atmosphere; 3: carbon disulfide; methyl iodide optical yield given as percent eeFurther stages;
参考文献
Kapeller, Dagmar C.; Hammerschmidt, Friedrich
Journal of Organic Chemistry, 2009 , vol. 74, # 6 p. 2380 - 2388
111-71-7
庚醛
+
100-46-9
→
反应条件
5730-02-9
反应条件
formic acid Eschweiler-Clarke reaction; 5 h; microwave irradiation;
参考文献
Torchy; Barbry
Journal of Chemical Research - Part S, 2001 , # 7 p. 292 - 293
111-71-7
庚醛
+
100-46-9
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反应条件
1286196-58-4
+
5730-02-9
反应条件
sodium tetrahydroborate in 1,2-dichloro-ethane
参考文献
Khan, Imran A.; Saxena, Anil K.
Journal of Organic Chemistry, 2013 , vol. 78, # 23 p. 11656 - 11669
111-71-7
庚醛
+
627-15-6
→
反应条件
36971-14-9
+
58396-45-5
反应条件
indium in water 16 h; Ambient temperature;
参考文献
Chen, Dong-Li; Li, Chao-Jun
Tetrahedron Letters, 1996 , vol. 37, # 3 p. 295 - 298
58396-18-2
+
111-71-7
庚醛
→
反应条件
58396-45-5
反应条件
(i) nBuLi, THF, (ii) /BRN= 1101528/, (iii) P(OEt)3; Multistep reaction;
参考文献
Meyers,A.I.; Ford,M.E.
Journal of Organic Chemistry, 1976 , vol. 41, p. 1735 - 1742
111-71-7
庚醛
+
95-54-5
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反应条件
5851-48-9
反应条件
sodium hydrogensulfite in N,N-dimethyl acetamide T=100°C; 2 h;
参考文献
Yamashita, Tomohiro; Yamada, Shozo; Yamazaki, Yasundo; Tanaka, Hideo
Synthetic Communications, 2009 , vol. 39, # 16 p. 2982 - 2988
111-71-7
庚醛
+
1516-58-1
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反应条件
5851-48-9
+
1022165-74-7
+
1072139-23-1
反应条件
1: 2-azidonitrobenzene With triphenylphosphine in diethyl ether T=20°C; 1 h; 2: heptanal in chloroform aza-Wittig reaction; 168 h; Heating; 3: With carbon monoxide; 1,3-bis-(diphenylphosphino)propane; 1,10-phenanthroline monohydrate; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide T=70°C; P=4560.31 Torr; 72 h; Further stages.;
参考文献
Wallace, Jeffery M.; Soederberg, Bjoern C.G.; Tamariz, Joaquin; Akhmedov, Novruz G.; Hurley, Mathew T.
Tetrahedron, 2008 , vol. 64, # 41 p. 9675 - 9684
111-71-7
庚醛
+
88-74-4
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反应条件
5851-48-9
反应条件
1: 2-nitro-aniline With ammonium formate; palladium in toluene T=120°C; 1 h; 2: heptanal in toluene T=4 - 20°C; 16 h;
参考文献
Weires, Nicholas A.; Boster, Jared; Magolan, Jakob
European Journal of Organic Chemistry, 2012 , # 33 p. 6508 - 6512
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