in water evapn. of water from aq. solns. of oxalic acid, boric acid, and LiOH (2:1:1 mol.); refluxed with CH3CN; filtered; dried in vac. oven at 100°C for 2 d;
参考文献
Xu, Wu; Wang, Li-Min; Nieman, Ronald A.; Angell, C. Austen
Journal of Physical Chemistry B, 2003 , vol. 107, # 42 p. 11749 - 11756
in neat (no solvent) byproducts: caesium borates, H2O; cesium iodide and boric acid were heated together to temp. in the range 400-1000 °C;; nitrogen-matrix IR of the obtained vapor products;;
参考文献
Nicholas
High temperature science, 1987 , vol. 24, # 3 p. 125 - 171
byproducts: sodium borate; reaction of Na with B(OH)3; no light phenomoneon observed;;
参考文献
Gmelin Handbook: Na: MVol., 36, page 144 - 145
Full Text Show Details
Gay-Lussac; Thenard
Recherches physico-chimiques, Paris 1811, Bd. 1, S. 318
Full Text Show Details
Gay-Lussac; Thenard
Recherches physico-chimiques, Paris 1811, Bd. 1, S. 50
CaH2 in neat (no solvent) byproducts: H2; react. under N2, slow addn. of the alcohol via syringe to B(OH)3 (ratio 3:1) and CaH2, cooling in a water bath, slow heating to 80 - 90°C for 12 h after abating the H2 gas evolution; distn. of the volatile products under reduced pressure (distn. pot temp. <= 120°C);
参考文献
Cole, T. E.; Quintanilla, R.; Rodewald, S.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990 , vol. 20, p. 55 - 64
