in neat (no solvent) Kinetics; byproducts: butene; thermal decompn. (452-505 K, sealed ampul); chromy.;
参考文献
Sokolovskii, A. E.; Baev, A. K.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 2093 - 2098
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 2336 - 2342
catalyst: (-)-3-exo-(dimethylamino)isoborneol in toluene toluene-soln. of catalyst added Bu2Zn at 30°C; after 15 min added Et2Zn; mixt. stirred for 10 min and cooled to 0°C; added benzaldehyde; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;
参考文献
Journal of the American Chemical Society, , vol. 111, # 11 p. 4028 - 4036
in toluene toluene-soln. of Zn-complex added Bu2Zn; mixt. stirred at -78°C; added benzaldehyde; mixt. stirred at 0°C for 6 h; quenched (water); analyzed by HPLC;
参考文献
Journal of the American Chemical Society, , vol. 111, # 11 p. 4028 - 4036
