3',4',5'-三甲氧基苯乙酮合成路线 （共 90 条）
反应条件
toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid in acetonitrile T=80°C; Baeyer-Villiger oxidation; 2 h; Further byproducts given;
参考文献
Bjorsvik, Hans-Rene; Occhipinti, Giovanni; Gambarotti, Cristian; Cerasino, Leonardo; Jensen, Vidar R.
Journal of Organic Chemistry, 2005 , vol. 70, # 18 p. 7290 - 7296
反应条件
dihydrogen peroxide; toluene-4-sulfonic acid; acetic acid T=80°C; Baeyer-Villiger oxidation; 1 h; Further byproducts given;
参考文献
Bjorsvik, Hans-Rene; Occhipinti, Giovanni; Gambarotti, Cristian; Cerasino, Leonardo; Jensen, Vidar R.
Journal of Organic Chemistry, 2005 , vol. 70, # 18 p. 7290 - 7296
反应条件
sodium azide; iodine; sodium hydrogencarbonate in water T=100°C; 2 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 355, # 18 p. 3591 - 3596
反应条件
1: AcOOH, HClO4, Ac2O / acetic acid 2: KOH / aq. ethanol / Heating View Scheme
参考文献
Huee,R. et al.
Bulletin de la Societe Chimique de France, 1970 , p. 3617 - 3624
反应条件
toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid in acetonitrile T=80°C; Baeyer-Villiger oxidation; 2 h; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 70, # 18 p. 7290 - 7296
反应条件
dihydrogen peroxide; toluene-4-sulfonic acid; acetic acid T=80°C; Baeyer-Villiger oxidation; 1 h; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 70, # 18 p. 7290 - 7296
反应条件
copper dichloride; lithium diisopropyl amide 1.) THF, -70 deg C, 2 h, 2.) THF, DMF, -70 deg C, 2 h; Yield given. Multistep reaction;
参考文献
Merck and Co., Inc.
Patent: US4757084 A1, 1988 ;
参考文献
Pettit,G.R.; Alkalay,D.S.
Journal of Organic Chemistry, 1960 , vol. 25, p. 1363 - 1365
反应条件
in ethanol T=20°C; 12 h; Reflux;
参考文献
Kamal, Ahmed; Dastagiri; Janaki Ramaiah; Surendranadha Reddy; Vijaya Bharathi; Kashi Reddy; Victor Prem Sagar; Lakshminarayan Reddy; Pushpavalli; Pal-Bhadra, Manika
European Journal of Medicinal Chemistry, 2011 , vol. 46, # 12 p. 5817 - 5824
反应条件
1: 60 percent / AlCl3 2: 60 percent 3: 45 percent 4: 85 percent / H+ / methanol View Scheme
参考文献
Topiwala, Upendra P.; Whiting, Donald A.
Journal of the Chemical Society, Chemical Communications, 1994 , # 21 p. 2443 - 2444
