2-氨基-4'-溴二苯甲酮合成路线 （共 22 条）
反应条件
hydrogenchloride; iron in ethanol; water 1 h; Reflux;
参考文献
Zhang, Jintang; Yu, Chenmin; Wang, Sujing; Wan, Changfeng; Wang, Zhiyong
Chemical Communications, 2010 , vol. 46, # 29 p. 5244 - 5246
反应条件
1: With acetic acid in water T=80°C; 2: With sodium carbonate T=20°C; Saturated solution;
参考文献
Organic Letters, , vol. 13, # 4 p. 709 - 711
反应条件
1: With boron trichloride in tetrachloroethane, 1,1,2,2- Sugasawa reaction; Cooling with iceReflux; 2: With hydrogenchloride; water in tetrachloroethane, 1,1,2,2- T=80°C; Sugasawa reaction; 1 h; Cooling with ice;
参考文献
Organic and Biomolecular Chemistry, , vol. 10, # 24 p. 4704 - 4711
反应条件
alkaline aqueous sodium hypobromite solution
参考文献
Journal of the American Chemical Society, , vol. 57, p. 2443,2446
反应条件
1.1: AlCl3, aluminium chloride / 0 °C 2.1: triethylamine / tetrahydrofuran / 0.5 h / -10 °C 2.2: 1.5 h / -10 °C 3.1: sodium azide / tetrahydrofuran; water / 3 h / -10 °C 4.1: acetic acid / water / 80 °C 4.2: 20 °C / Saturated solution View Scheme
参考文献
Organic Letters, , vol. 13, # 4 p. 709 - 711
反应条件
1.1: AlCl3, aluminium chloride / 0 °C 2.1: triethylamine / tetrahydrofuran / 0.5 h / -10 °C 2.2: 1.5 h / -10 °C 3.1: sodium azide / tetrahydrofuran; water / 3 h / -10 °C 4.1: acetic acid / water / 80 °C 4.2: 20 °C / Saturated solution View Scheme
参考文献
Organic Letters, , vol. 13, # 4 p. 709 - 711
反应条件
1.1: triethylamine / tetrahydrofuran / 0.5 h / -10 °C 1.2: 1.5 h / -10 °C 2.1: sodium azide / tetrahydrofuran; water / 3 h / -10 °C 3.1: acetic acid / water / 80 °C 3.2: 20 °C / Saturated solution View Scheme
参考文献
Organic Letters, , vol. 13, # 4 p. 709 - 711
反应条件
1.1: sodium azide / tetrahydrofuran; water / 3 h / -10 °C 2.1: acetic acid / water / 80 °C 2.2: 20 °C / Saturated solution View Scheme
参考文献
Organic Letters, , vol. 13, # 4 p. 709 - 711
反应条件
aluminium trichloride Erhitzen des Reaktionsprodukts mit wss. Schwefelsaeure und Essigsaeure;
参考文献
Journal of the American Chemical Society, , vol. 57, p. 2443,2446
反应条件
1: With silver hexafluoroantimonate; {RuCl2(1-methyl-4-(1-methylethyl)benzene)}2; copper (II) acetate monohydrate in 1,2-dichloro-ethane T=100°C; 24 h; Inert atmosphereSchlenk technique; 2: With sulfuric acid T=0 - 20°C; 2 h; Inert atmosphereSchlenk technique; 3: With sodium hydrogencarbonate Inert atmosphereSchlenk technique;
参考文献
Chemical Communications, , vol. 49, # 45 p. 5225 - 5227
