2-甲基-3-丁烯-2-醇合成路线 （共 471 条）
反应条件
1: NaH / xylene / Heating
2: 14 percent / 1.5 h / 5 °C / Irradiation; photolysis in quartz NMR tube with a 45O-W, medium pressure Hanovia Hg lamp
3: 90 percent Chromat. / diethyl ether / 4 h / -40 - -20 °C
View Scheme
参考文献
Tzeng, Dongjaw; Weber, William P.
Journal of Organic Chemistry, 1981 , vol. 46, # 4 p. 693 - 696
反应条件
(η3-allyl)2Pd(cod)BF4; C21H10F12NOP in toluene
T=80°C; 24 h; Inert atmosphere;
参考文献
Usui, Ippei; Schmidt, Stefan; Keller, Manfred; Breit, Bernhard
Organic Letters, 2008 , vol. 10, # 6 p. 1207 - 1210
反应条件
Montmorillonite K 10
T=20°C; 216 h; Further byproducts given;
参考文献
Desaubry, Laurent; Nakatani, Yoichi; Ourisson, Guy
Tetrahedron Letters, 2003 , vol. 44, # 36 p. 6959 - 6961
反应条件
trifluoroacetic acid in dichloromethane
T=0°C; 0.333333 h; reaction with isopentenyl derivatives and their homologs in var. solvents; Product distribution;
参考文献
Badet,B.; Julia,M.; Mallet,J.M.
Tetrahedron, 1988 , vol. 44, p. 2913
反应条件
mesoporous silica containing bimetallic Cu-Al (CuAl-KIT-5) in 1,2-dichloro-ethane
T=60°C; 16 h;
参考文献
Varghese, Shaji; Anand, Chokkalingam; Dhawale, Dattatray; Mane, Gurudas P.; Wahab, Mohammad A.; Mano, Ajayan; Raj, George Allen Gnana; Nagarajan, Samuthira; Vinu, Ajayan
ChemCatChem, 2013 , vol. 5, # 4 p. 899 - 902
反应条件
boron trifluoride diethyl etherate in 1,4-dioxane
参考文献
Hlubucek,J. et al.
Australian Journal of Chemistry, 1971 , vol. 24, p. 2355 - 2363
反应条件
[PtCl2(η2:η2-cycloocta-1,5-diene)]; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in N,N-dimethyl-formamide
T=60°C; 1 h; Microwave irradiation;
参考文献
Ohshima, Takashi; Miyamoto, Yoshiki; Ipposhi, Junji; Nakahara, Yasuhito; Utsunomiya, Masaru; Mashima, Kazushi
Journal of the American Chemical Society, 2009 , vol. 131, # 40 p. 14317 - 14328
反应条件
Ti(NMe2)4 in toluene
T=160°C; 10 h; in sealed tube;
参考文献
Ramanathan, Balasubramanian; Odom, Aaron L.
Journal of the American Chemical Society, 2006 , vol. 128, # 29 p. 9344 - 9345
反应条件
tricyclo[3.3.1.13,7 ]-decane-1-carboxylic acid; triphenylphosphine; bis(acetylacetonato) palladium in water
0.5 h; Heating;
参考文献
Yang, Shyh-Chyun; Hsu, Yi-Chun; Gan, Kim-Hong
Tetrahedron, 2006 , vol. 62, # 17 p. 3949 - 3958
反应条件
1: hydrogen bromide
2: benzene
3: concentrated methanolic KOH-solution
View Scheme
参考文献
Claisen
Journal fuer Praktische Chemie (Leipzig), 1922 , vol. <2> 105, p. 72
Chemische Berichte, 1925 , vol. 58, p. 279 Anm. 15
