2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
反应条件
1: 53 percent / calcium chloride; hydroquinone / aq. HCl / 1 h / cooling 2: 71 percent / zinc; aq. hydrochloride acid; aq. copper sulfate / ethanol; butan-1-ol / 38 - 42 °C View Scheme
参考文献
Chengebroyen, Jaganaiden; Linke, Myriam; Robitzer, Mike; Sirlin, Claude; Pfeffer, Michel
Journal of Organometallic Chemistry, 2003 , vol. 687, # 2 p. 313 - 321
反应条件
hydroxylamine in water; isopropyl alcohol T=140°C; Cope-type hydroamination; Inert atmosphereMicrowave irradiation; regioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 130, # 52 p. 17893 - 17906
反应条件
hydroxylamine in water; isopropyl alcohol T=140°C;
参考文献
Loiseau, Francis; Beauchemin, Andre M.
Organic Syntheses, 2013 , vol. 90, p. 87 - 95
反应条件
hydrogen; palladium-copper; silica gel in ethanol T=25°C; P=760 Torr; Kinetics;
参考文献
Spee; Boersma; Meijer; Slagt; Van Koten; Geus
Journal of Organic Chemistry, 2001 , vol. 66, # 5 p. 1647 - 1656
反应条件
hydrogen; palladium membrane T=29.9°C; electrochemical reduction; Kinetics;
参考文献
Lebedewa
Zhurnal Obshchei Khimii, 1948 , vol. 18, p. 1162
Zhurnal Obshchei Khimii, 1949 , vol. 19, p. 70,71
Chem.Abstr., 1949 , p. 994,1950 461
Full Text Show Details
Lebedewa
Zhurnal Obshchei Khimii, 1949 , vol. 19, p. 70,71
Chem.Abstr., 1950 , p. 461
反应条件
hydrogen; magnesium oxide; copper in ethanol T=99.9°C; P=15001.2 Torr; other catalysts (Ag/MgO, Au/MgO); Rate constantProduct distribution;
参考文献
Journal of applied chemistry of the USSR, , vol. 57, # 2 pt 2 p. 426 - 428
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tris(4-methylphenyl)-phosphine in tetrahydrofuran T=80°C; Sonogashira Cross-Coupling; 6 h; Inert atmosphereSchlenk technique; SolventReagent/catalyst;
参考文献
Caporale, Andrea; Tartaggia, Stefano; Castellin, Andrea; De Lucchi, Ottorino
Beilstein Journal of Organic Chemistry, 2014 , vol. 10, p. 384 - 393
反应条件
copper(l) iodide; bis(triphenylphosphine)palladium(II)-chloride; triethylamine T=40°C; 2 h;
参考文献
Takalo, Harri; Kankare, Jouko; Haenninen, Elina
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1988 , vol. 42, # 7 p. 448 - 454
反应条件
copper(l) iodide; triethylamine in N,N-dimethyl-formamide T=20°C; 16 h; Inert atmosphere;
参考文献
Li, Hongling; Wang, Lailai; Yang, Min; Qi, Yanxing
Catalysis Communications, 2012 , vol. 17, p. 179 - 183
反应条件
potassium hydroxide; diethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide 2.) MeOH, reflux; Multistep reaction;
参考文献
Journal of Physical Chemistry, , vol. 98, # 3 p. 748 - 751
