2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine; triphenylphosphine in tetrahydrofuran T=20°C; Inert atmosphere;
参考文献
Li, Zhen; Li, Zhong'An; Wu, Wenbo; Qiu, Guofu; Yu, Gui; Liu, Yunqi; Ye, Cheng; Qin, Jingui
Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 9 p. 1977 - 1987
反应条件
1.1: sodium hypochlorite; triethylamine / H2O; CHCl3 / 0 - 4 °C 2.1: hydrogen / Pd/C / methanol / 10 h 2.2: 70 percent / aqueous hydrochloric acid / H2O / 3 h View Scheme
参考文献
Chimichi, Stefano; Boccalini, Marco; Cosimelli, Barbara; Viola, Giampietro; Vedaldi, Daniela; Dall'Acqua, Francesco
Tetrahedron Letters, 2002 , vol. 43, # 42 p. 7473 - 7476
反应条件
toluene-4-sulfonic acid; triphenylphosphine; palladium diacetate in tetrahydrofuran T=100°C; P=20685.9 Torr; 48 h; Yields of byproduct given;
参考文献
Xiao, Wen-Jing; Alper, Howard
Journal of Organic Chemistry, 1997 , vol. 62, # 11 p. 3422 - 3423
反应条件
1: 3.33 h / 20 - 145 °C / Inert atmosphere 2: lithium aluminium tetrahydride / diethyl ether / 1 h / 0 °C / Inert atmosphere 3: triethylamine / tetrahydrofuran / 1 h / 0 °C / Inert atmosphere 4: potassium carbonate / acetonitrile / 16 h / Reflux; Inert atmosphere View Scheme
参考文献
Garcia, Pierre; Harrak, Youssef; Diab, Lisa; Cordier, Pierre; Ollivier, Cyril; Gandon, Vincent; Malacria, Max; Fensterbank, Louis; Aubert, Corinne
Organic Letters, 2011 , vol. 13, # 11 p. 2952 - 2955
反应条件
tetrafluoroboric acid; silica gel T=20°C; 2 h;
参考文献
Chakraborti, Asit K.; Sharma, Lalima; Gulhane, Rajesh; Shivani
Tetrahedron, 2003 , vol. 59, # 39 p. 7661 - 7668
反应条件
perchloric acid T=20°C; 6 h;
参考文献
Chakraborti, Asit K.; Gulhane, Rajesh
Chemical Communications, 2003 , # 15 p. 1896 - 1897
反应条件
aluminum oxide; silica gel; zirconium oxide
参考文献
Eastman Kodak Co.
Patent: US2685598 , 1951 ;
参考文献
Bergmann; Herman
Journal of Applied Chemistry, 1953 , vol. 3, p. 42,48
反应条件
ammonium hydroxide; zinc(II) chloride 1.) 40 deg C, 2 h, 2.) 0 deg C; Yield given. Multistep reaction;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 37, # 11 p. 2343 - 2346
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 11 p. 2600 - 2604
反应条件
copper; calcium chloride; copper dichloride; hydrogenchloride T=0°C; 1 h;
参考文献
Stulgies, Balder; Prinz, Peter; Magull, Joerg; Rauch, Karsten; Meindl, Kathrin; Ruehl, Stephan; De Meijere, Armin
Chemistry - A European Journal, 2005 , vol. 11, # 1 p. 308 - 320
