2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
反应条件
1: phosphoric acid
2: palladium/barium carbonate; petroleum ether / Hydrogenation
View Scheme
参考文献
Hennion et al.
Journal of Organic Chemistry, 1956 , vol. 21, p. 1142
参考文献
Surzur,J.-M.; Teissier,P.
Bulletin de la Societe Chimique de France, 1970 , # 4 p. 1611 - 1616
反应条件
piperidine; caesium carbonate; [(P{(C6H11)3})2Pd(Cl)2] in dimethyl sulfoxide
T=120°C; Sonogashira coupling; 12 h;
参考文献
Yi, Chenyi; Hua, Ruimao; Zeng, Hanxiang; Huang, Qiufeng
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 10 p. 1738 - 1742
反应条件
sodium hydroxide; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); phenylmethyltriethylammonium bromide in benzene
34 h; Heating;
参考文献
Ng, Siu-Choon; Ong, Teng-Teng; Chan, Hardy S. O.
Journal of Materials Chemistry, 1998 , vol. 8, # 12 p. 2663 - 2669
反应条件
boron trifluoride diethyl etherate in toluene
T=100°C; 3 h;
参考文献
Haak, Edgar
European Journal of Organic Chemistry, 2008 , # 5 p. 788 - 792
反应条件
palladium on activated charcoal; copper(l) iodide; triethylamine in N,N-dimethyl-formamide
T=75 - 80°C; 3 h; Product distribution; Further Variations:ReagentsSolvents;
参考文献
Venkataraman, Subramanian; Barange, Deepak Kumar; Pal, Manojit
Tetrahedron Letters, 2006 , vol. 47, # 41 p. 7317 - 7322
反应条件
1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine; triphenylphosphine / 4 h / 50 °C / Inert atmosphere; Sealed flask
2: iodine / dichloromethane / -20 - 25 °C
View Scheme
参考文献
Zhou, Chao; Chen, Xiaopeng; Lu, Ping; Wang, Yanguang
Tetrahedron, 2012 , vol. 68, # 13 p. 2844 - 2850
反应条件
1.1: triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / tetrahydrofuran / 0.5 h / 20 °C / |Inert atmosphere
1.2: 6 h / |Inert atmosphere
2.1: [Cp*Ir(SnCl3)2{SnCl2(H2O)2}] / 1,2-dichloro-ethane / 80 °C / |Inert atmosphere; |Schlenk technique
View Scheme
参考文献
Maity, Arnab Kumar; Chatterjee, Paresh Nath; Roy, Sujit
Tetrahedron, 2013 , vol. 69, # 2 p. 942 - 956
反应条件
potassium hydroxide; diethyl ether
参考文献
Babajan
Izv. Armjansk. Akad.Chem.Abstr., p. 121,144
Izv. Armjansk. Akad.Chem.Abstr., 1946 , p. 3395
Full Text Show Details
Sacharowa
Zhurnal Obshchei Khimii, 1941 , vol. 11, p. 939,945
Chem.Abstr., 1943 , p. 355
参考文献
Sacharowa
Zhurnal Obshchei Khimii, 1941 , vol. 11, p. 939,945
Chem.Abstr., 1943 , p. 355
