2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran
T=25°C; Sonogashira coupling; 6 h;
参考文献
Gallagher, William P.; Maleczka Jr., Robert E.
Journal of Organic Chemistry, 2003 , vol. 68, # 17 p. 6775 - 6779
反应条件
triethylamine; copper(I) bromide; lithium bromide in tetrahydrofuran; dimethyl sulfoxide
T=95°C; Sonogashira Cross-Coupling; 13 h; Inert atmosphere; Reagent/catalystSolventTemperatureTimeConcentration;
参考文献
Parshina; Tantsyrev; Grishchenko; Trofimov
Russian Journal of Organic Chemistry, 2013 , vol. 49, # 3 p. 412 - 416
Zh. Org. Khim., 2013 , vol. 49, # 3 p. 425 - 428,4
反应条件
copper(l) iodide; N,N,N',N,-tetramethylethylenediamine; triethylamine in acetone
T=20°C; 20 h;
参考文献
Zhang, Songlin; Liu, Xiaoyan; Wang, Tongqiang
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 9 p. 1463 - 1466
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine
12 h;
参考文献
Sarkar; Manjunath; Kamath; Bhagwat; Babu; Rajalakshmi; Talwar
Indian Journal of Chemistry - Section B Organic Chemistry Including Medicinal Chemistry, 1991 , vol. 30, # 3 p. 360 - 362
参考文献
Chodkiewicz; Cadiot
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1955 , vol. 241, p. 1055
反应条件
elektrolytische Reduktion an Nickelkathoden.Electrolysis;
参考文献
Lebedewa
Doklady Akademii Nauk SSSR, 1944 , vol. 42, p. 70
Chem.Abstr., 1945 , p. 4287
Full Text Show Details
Lebedewa
Doklady Akademii Nauk SSSR, vol. 42, p. 71
Chem.Abstr., 1945 , p. 4287
反应条件
T=25 - 40°C; Kinetics;
参考文献
Klebanskii et al.
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1958 , vol. 31, p. 1869;engl.Ausg.S.1858
Full Text Show Details
Klebanskii et al.
Zhurnal Obshchei Khimii, 1957 , vol. 27, p. 2977,2980; engl. Ausg. S. 3008, 3011
参考文献
Salkind; Aisikowitsch
Zhurnal Obshchei Khimii, 1937 , vol. 7, p. 227,232
Chem. Zentralbl., 1937 , vol. 108, # I p. 4783
反应条件
1: PCl3 / CH2Cl2
2: aq. NaHCO3
3: aq. HCl
View Scheme
参考文献
Macomber,R.S.; Kennedy,E.R.
Journal of Organic Chemistry, 1976 , vol. 41, p. 3191 - 3197
反应条件
sodium hydroxide; 2,2'-azo-bisisobutyronitrile in dichloromethane
T=0 - 20°C; 3 h; Product distribution; Further Variations:SolventsTemperaturesreaction time;
参考文献
Calleja-Rubio; Crette; Blancou
Synthesis, 2003 , # 3 p. 361 - 364
