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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
1151545-40-2
合成路线
(共 9 条)
98-01-1
糠醛
+
1151545-40-2
→
反应条件
39511-08-5
反-3-(2-呋喃基)丙烯醛
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: furfural in toluene T=-78 - 20°C; 14 h; Inert atmosphere; Further stages;
参考文献
Valenta, Petr; Drucker, Natalie A.; Bode, Jeffrey W.; Walsh, Patrick J.
Organic Letters, 2009 , vol. 11, # 10 p. 2117 - 2119
1151545-40-2
+
100-52-7
苯甲醛
→
反应条件
14371-10-9
桂皮醛
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: benzaldehyde in toluene T=-78 - 20°C; 14 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether; toluene T=0°C; pH=> 4; Inert atmosphere;
参考文献
Organic Letters, , vol. 11, # 10 p. 2117 - 2119
104-53-0
苯丙醛
+
1151545-40-2
→
反应条件
33046-84-3
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: 3-phenyl-propionaldehyde in toluene T=-78 - 20°C; 14 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether; toluene T=0°C; pH=> 4; Inert atmosphere;
参考文献
Valenta, Petr; Drucker, Natalie A.; Bode, Jeffrey W.; Walsh, Patrick J.
Organic Letters, 2009 , vol. 11, # 10 p. 2117 - 2119
119-61-9
二苯甲酮
+
1151545-40-2
→
反应条件
1210-39-5
β-苯基肉桂醛
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: benzophenone in toluene T=-78 - 20°C; 14 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether; toluene T=0°C; pH=> 4; Inert atmosphere;
参考文献
Valenta, Petr; Drucker, Natalie A.; Bode, Jeffrey W.; Walsh, Patrick J.
Organic Letters, 2009 , vol. 11, # 10 p. 2117 - 2119
1151545-40-2
+
108-94-1
环己酮
→
反应条件
1713-63-9
环己基亚基乙醛
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: cyclohexanone in toluene T=-78 - 20°C; 14 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether; toluene T=0°C; pH=> 4; Inert atmosphere;
参考文献
Valenta, Petr; Drucker, Natalie A.; Bode, Jeffrey W.; Walsh, Patrick J.
Organic Letters, 2009 , vol. 11, # 10 p. 2117 - 2119
75-97-8
频哪酮
+
1151545-40-2
→
反应条件
1086258-92-5
+
65275-95-8
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: 3,3-dimethyl-butan-2-one in toluene T=-78 - 20°C; 14 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether; toluene T=0°C; pH=> 4; Inert atmosphere; optical yield given as percent de;
参考文献
Valenta, Petr; Drucker, Natalie A.; Bode, Jeffrey W.; Walsh, Patrick J.
Organic Letters, 2009 , vol. 11, # 10 p. 2117 - 2119
1151545-40-2
+
1846-68-0
2-辛醛
→
反应条件
78651-47-5
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: oct-2-ynal in toluene T=-78 - 20°C; 14 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether; toluene T=0°C; pH=> 4; Inert atmosphere;
参考文献
Valenta, Petr; Drucker, Natalie A.; Bode, Jeffrey W.; Walsh, Patrick J.
Organic Letters, 2009 , vol. 11, # 10 p. 2117 - 2119
1151545-40-2
+
643-79-8
邻苯二甲醛
→
反应条件
61650-52-0
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: phthalic carbaldehyde in toluene T=-78 - 20°C; 14 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether; toluene T=0°C; pH=> 4; Inert atmosphere;
参考文献
Valenta, Petr; Drucker, Natalie A.; Bode, Jeffrey W.; Walsh, Patrick J.
Organic Letters, 2009 , vol. 11, # 10 p. 2117 - 2119
498-60-2
3-糠醛
+
1151545-40-2
→
反应条件
54355-99-6
反应条件
1: tris(ethoxyvinyl)borane With diethylzinc in toluene T=-78°C; 0.333333 h; Inert atmosphere; 2: furan-3-carboxaldehyde in toluene T=-78 - 20°C; 14 h; Inert atmosphere; Further stages;
参考文献
Valenta, Petr; Drucker, Natalie A.; Bode, Jeffrey W.; Walsh, Patrick J.
Organic Letters, 2009 , vol. 11, # 10 p. 2117 - 2119