2-苯磺酰-1,3-环庚二烯合成路线 （共 5 条）
反应条件
triethylamine in acetonitrile T=20°C; 24 h;
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
反应条件
boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid in dichloromethane Ambient temperature1) 17 h, 2) 15 min;
参考文献
Baeckvall, Jan-E.; Najera, Carmen; Yus, Miguel
Tetrahedron Letters, 1988 , vol. 29, # 12 p. 1445 - 1448
反应条件
1.1: Na2WO4; aq. H3PO4; NaBr / PhPO(OH)2; H2O2 / 15 - 18 °C 1.2: aq. Na2WO4; PhPO(OH)2; H2O2 / tricaprylylmethylammonium hydrogensulfate / toluene / 15 h 1.3: toluene; H2O / 2 h / 20 - 60 °C 2.1: 1.11 kg / DABCOTM / H2O / 36 h / 20 °C View Scheme
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
反应条件
1.1: Montmorillonite KSF / toluene / 24 h / Heating 2.1: Na2WO4; aq. H3PO4; NaBr / PhPO(OH)2; H2O2 / 15 - 18 °C 2.2: aq. Na2WO4; PhPO(OH)2; H2O2 / tricaprylylmethylammonium hydrogensulfate / toluene / 15 h 2.3: toluene; H2O / 2 h / 20 - 60 °C 3.1: 1.11 kg / DABCOTM / H2O / 36 h / 20 °C View Scheme
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
反应条件
1.1: Montmorillonite KSF / toluene / 24 h / Heating 2.1: Na2WO4; aq. H3PO4; NaBr / PhPO(OH)2; H2O2 / 15 - 18 °C 2.2: aq. Na2WO4; PhPO(OH)2; H2O2 / tricaprylylmethylammonium hydrogensulfate / toluene / 15 h 2.3: toluene; H2O / 2 h / 20 - 60 °C 3.1: 1.11 kg / DABCOTM / H2O / 36 h / 20 °C View Scheme
参考文献
Meyers, David J.; Fuchs, Philip L.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 200 - 204
