triphenylphosphine in dichloromethane Kinetics; byproducts: CO2, (CH3)3N; (N2); at 14.5 °C; react. in soln. monitored IR and UV spect.; react. mechanism discussed; not isolated;
参考文献
Shi, Yan-Lung; Gao, Yi-Ci; Shi, Qi-Zhen; Kershner, David L.; Basolo, Fred
Organometallics, 1987 , vol. 6, p. 1528 - 1531
in dichloromethane under N2, Me3NO in CH2Cl2 was added dropwise to CH2Cl2 soln. of Os-complex (molar ratio was 2:1), stirring at room temp. for 20 h; solvent was removed in vac., chromy. on silica, elution with hexane/CH2Cl2 (7:3, v/v), recrystd. from hexane/CH2Cl2 at -20 °C;
in N,N-dimethyl-formamide 24 h; Ambient temperature;
参考文献
Ivanova, T. M.; Shein, S. M.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, p. 1055 - 1060
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 6 p. 1221 - 1228
Ivanova, T. M.; Shein, S. M.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, p. 1055 - 1060
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 6 p. 1221 - 1228
166 h; Ambient temperatureother temperature, effect of peroxides; KineticsProduct distribution;
参考文献
Ivanova, T. M.; Shein, S. M.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, p. 1055 - 1060
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 6 p. 1221 - 1228
