2,2,6,6-四甲基环己酮合成路线 （共 45 条）
反应条件
in n-heptane T=80°C; 24 h; Product distribution;
参考文献
Shineer, Cristofer S.; Berks, Andrew H.; Fisher, Allison, M.
Journal of the American Chemical Society, 1988 , vol. 110, # 3 p. 957 - 958
反应条件
in pentane T=0°C; 20 h; Irradiation;
参考文献
Hinsberg, William D.; Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1982 , vol. 104, # 3 p. 766 - 773
反应条件
1: With tris[3,5-bis(2,2'',6,6''-tetramethyl-m-terphenyl-5'-yl)phenyl]phosphine; copper(l) chloride; sodium t-butanolate in toluene T=20°C; 2 h; Inert atmosphere; 2: With hydrogenchloride; methanol in toluene Inert atmosphere;
参考文献
Fujihara, Tetsuaki; Semba, Kazuhiko; Terao, Jun; Tsuji, Yasushi
Angewandte Chemie - International Edition, 2010 , vol. 49, # 8 p. 1472 - 1476
反应条件
KNH2; sodium amide beim Schmelzen;
参考文献
Freidlin; Balandin; Lebedewa
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1941 , p. 167
Chem.Abstr., 1943 , p. 3749
Chem. Zentralbl., 1942 , vol. 113, # I p. 1508
参考文献
Freidlin; Balandin; Lebedewa
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1941 , p. 167
Chem.Abstr., 1943 , p. 3749
Chem. Zentralbl., 1942 , vol. 113, # I p. 1508
反应条件
1: (i) Mg, THF, (ii) /BRN= 1906567/ 2: HCO2H / 4 h / Heating 3: air, KOH / methanol View Scheme
参考文献
de Botton,M.
Bulletin de la Societe Chimique de France, 1966 , p. 2212 - 2217
反应条件
potassium hydroxide; 18-crown-6 ether in toluene
T=70°C; 1 h;
参考文献
Lissel, Manfred; Neumann, Beate; Schmidt, Stefan
Liebigs Annalen der Chemie, 1987 , p. 263 - 264
反应条件
ozone in diethyl ether
T=-70°C;
参考文献
Kawamura, Shin-Ichi; Yamakoshi, Hideyuki; Abe, Manabu; Masuyama, Araki; Nojima, Masatomo
Tetrahedron, 2002 , vol. 58, # 5 p. 891 - 896
反应条件
CC-2; water in acetonitrile
T=20°C; 0.666667 h;
参考文献
Gupta, Arvind K.; Acharya, Jyotiranjan; Pardasani, Deepak; Dubey, Devendra K.
Journal of Chemical Research, 2007 , # 7 p. 411 - 414
反应条件
oxygen in dichloromethane
T=-78°C; 2 h; Irradiationdye-sensitized oxidation;
参考文献
Rao, V. Jayathirtha; Ramamurthy, V.; Schaumann, E.; Nimmesgern, H.
Journal of Organic Chemistry, 1984 , vol. 49, # 4 p. 615 - 621
