1198183-95-7合成路线 （共 10 条）
反应条件
palladium diacetate; caesium carbonate; 1,2-bis-(diphenylphosphino)ethane in 1-methyl-pyrrolidin-2-one T=100°C; 16 h; Inert atmosphere;
参考文献
Ackermann, Lutz; Barfuesser, Sebastian; Pospech, Jola
Organic Letters, 2010 , vol. 12, # 4 p. 724 - 726
反应条件
palladium diacetate; caesium carbonate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in 1,4-dioxane T=110°C; 24 h; Inert atmosphere; chemoselective reaction;
参考文献
Ackermann, Lutz; Mehta, Vaibhav P.
Chemistry - A European Journal, 2012 , vol. 18, # 33 p. 10230 - 10233
反应条件
1: 3-trifluoromethyl-aniline With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in toluene T=20°C; 0.166667 h; Inert atmosphere; 2: phenyl 1H-imidazole-1-sulfonate in toluene T=105°C; 17 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 13, # 7 p. 1784 - 1786
反应条件
1: 3-methoxy-aniline With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in toluene T=20°C; 0.166667 h; Inert atmosphere; 2: phenyl 1H-imidazole-1-sulfonate in toluene T=105°C; 17 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 13, # 7 p. 1784 - 1786
反应条件
1: 4-methoxy-aniline With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in toluene T=20°C; 0.166667 h; Inert atmosphere; 2: phenyl 1H-imidazole-1-sulfonate in toluene T=105°C; 17 h; Inert atmosphere;
参考文献
Ackermann, Lutz; Sandmann, Rene; Song, Weifeng
Organic Letters, 2011 , vol. 13, # 7 p. 1784 - 1786
反应条件
1: o-toluidine With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in toluene T=20°C; 0.166667 h; Inert atmosphere; 2: phenyl 1H-imidazole-1-sulfonate in toluene T=105°C; 17 h; Inert atmosphere;
参考文献
Ackermann, Lutz; Sandmann, Rene; Song, Weifeng
Organic Letters, 2011 , vol. 13, # 7 p. 1784 - 1786
反应条件
C26H16Cl6N2O2Pd2; tetrabutylammomium bromide; potassium hydroxide in methanol; water T=110°C; Suzuki coupling; 0.333333 h; Microwave irradiation;
参考文献
Civicos, Jose Francisco; Alonso, Diego A.; Najera, Carmen
European Journal of Organic Chemistry, 2012 , # 19 p. 3670 - 3676
反应条件
1: 4-chloro-aniline With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in toluene
T=20°C; 0.166667 h; Inert atmosphere;
2: phenyl 1H-imidazole-1-sulfonate in toluene
T=105°C; 17 h; Inert atmosphere;
参考文献
Ackermann, Lutz; Sandmann, Rene; Song, Weifeng
Organic Letters, 2011 , vol. 13, # 7 p. 1784 - 1786
反应条件
1: 3-nitro-aniline With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in toluene
T=20°C; 0.166667 h; Inert atmosphere;
2: phenyl 1H-imidazole-1-sulfonate in toluene
T=105°C; 17 h; Inert atmosphere;
参考文献
Ackermann, Lutz; Sandmann, Rene; Song, Weifeng
Organic Letters, 2011 , vol. 13, # 7 p. 1784 - 1786
反应条件
SPhos; C16H16Cl2N2O4Pd2; N-hexadecyl-N,N,N-trimethylammonium bromide; triethylamine in water
T=130°C; Sonogashira Cross-Coupling; 0.5 h; Microwave irradiation;
参考文献
Civicos, Jose F.; Alonso, Diego A.; Najera, Carmen
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 1 p. 203 - 208
