(1,5-环辛二烯)氯铑(I)二聚体合成路线 （共 52 条）
反应条件
in ethanol; water in a microwave oven (Fischer-Porter reaction vessel) at 140°C for 0.5 min; elem. anal.;
参考文献
Baghurst, David R.; Mingos, D. Michael P.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1992 , # 7 p. 1151 - 1156
反应条件
HCl in methanol byproducts: 3,5-dimethylpyrazole hydrochloride; soln. of Rh-complex was frozen by liquid N2, anhydous HCl was added, warmed to room temp.; ppt. filtered off, washed with methanol;
参考文献
Leung, Ping Y.; Peterson, Louis K.
Journal of Organometallic Chemistry, 1981 , vol. 219, # 3 p. 409 - 420
反应条件
in dichloromethane (N2), after addn. stirred for 2 h, reduced volume, added petroleum ether-diethyl ether (1:1); filtered, washed with diethyl ether, dried in vac., ((C8H12)RhCl)2 recovered from mother liquor; elem. anal.;
参考文献
Arena, Carmela Grazia; Rotondo, Enrico; Faraone, Felice; Lanfranchi, Maurizio; Tiripicchio, Antonio
Organometallics, 1991 , vol. 10, p. 3877 - 3885
反应条件
in dichloromethane (N2); dropwise addn. of the Pd-complex to the Rh-complex in CH2Cl2, stirring for 1 h; the volume of the soln. is reduced, addn. of diethyl ether, filtration, washing (diethyl ether), drying in vac., elem. anal.;
参考文献
Inorganic Chemistry, , vol. 31, p. 4797 - 4802
反应条件
in tetrahydrofuran N2-atmosphere, 5°C; evapn., extg. (hexane), filtering, evapn., extg. (C6H6), evapn.;
参考文献
Tetrick, Stephen M.; Xu, Chongfu; Pinkes, John R.; Cutler, Alan R.
Organometallics, 1998 , vol. 17, # 9 p. 1861 - 1867
反应条件
HgCl2 in dichloromethane instant reaction; no sepn. of metal-contg. products (similar soly.);
参考文献
Organometallics, , vol. 7, p. 1957 - 1966
反应条件
in dichloromethane byproducts: AgCl; (N2); addn. of the Ag-salt to a stirred soln. of the Au-complex in CH2Cl2, stirring for 10 min, filtration from AgCl, addn. of the filtrate to a soln. of the Rh-complex in CH2Cl2; the volume of the soln. is reduced, pptn. by addn. of diethyl ethergive the Au complex, the Rh complex is obtained from the mother liquor, elem. anal.;
参考文献
Inorganic Chemistry, , vol. 31, p. 4797 - 4802
反应条件
in dichloromethane (N2); addn. of the Pd-complex to the Rh-complex in CH2Cl2, stirring for 1 h; the volume of the soln. is reduced, addn. of diethyl ether, filtration, washing (diethyl ether), drying in vac., elem. anal.;
参考文献
Arena, Carmela Grazia; Faraone, Felice; Lanfranchi, Maurizio; Rotondo, Enrico; Tiripicchio, Antonio
Inorganic Chemistry, 1992 , vol. 31, p. 4797 - 4802
反应条件
HCl in benzene HCl is bubbled for 1 min through a soln. of Rh complex.; addn. of water, sepn. of layers; evapn. of benzene layer yields (RhCl(COD))2, ammonium salt of aryl compound is obtained from water layer.;
参考文献
Organometallics, , vol. 7, p. 1957 - 1966
反应条件
hydrogenchloride in benzene byproducts: [p-tolyl-NH=CH-NH-tolyl-p]Cl; HCl gas was bubbled through a benzene soln. of Rh-complex for 3 h; ppt. (amidinium chloride) was filtered off, washed with benzene and crystd. from MeOH/Et2O, (Rh(COD)Cl)2 was obtained from the supernatant liquor;
参考文献
Journal of Organometallic Chemistry, , vol. 224, # 3 p. 305 - 312
