aluminium; aluminium trichloride in neat (no solvent) byproducts: Al(OC6H5)3; High Pressure; heating to 180°C under 2000 psi H2-pressure for 1h; filtration;; separation of product at 97°C and 2 Torr;;
参考文献
Ashby, E. C.; Foster, W. E.
Journal of the American Chemical Society, 1962 , vol. 84, p. 3407 - 3408
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Gmelin Handbook: B: B-Verb.14, 3.8.1.2.1, page 94 - 97
HRh(dmpe)2 in tetrahydrofuran T=50°C; 14 h; Inert atmosphere;
参考文献
Mock, Michael T.; Potter, Robert G.; Camaioni, Donald M.; Li, Jun; Dougherty, William G.; Kassel, W. Scott; Twamley, Brendan; DuBois, Daniel L.
Journal of the American Chemical Society, 2009 , vol. 131, # 40 p. 14454 - 14465
triethyl borane in mineral oil addn. of a small amount of B(C2H5)3 and N(C2H5)3 to NaH in mineral oil at 70°C, addn. of BCl3 at 70-80°C while stirring;; separation by distn.;;
magnesium; mercury dichloride in 2-methyl cyclohexane byproducts: Mg(O-i-C4H9)2; High Pressure; heating to 300°C under 1825 psi H2 pressure;; separation of product by distn.;;
参考文献
Gmelin Handbook: B: B-Verb.14, 3.8.1.2.1, page 94 - 97
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Continental Oil Co.
Patent: US3136820 , 1964 ;
C. A., 1964 , vol. 61, p. 6919
