(苯甲酸甲酯)三基羰基铬合成路线 （共 17 条）
反应条件
catalyst: CH3COOC4H9 in decalin byproducts: CO; (Ar); refluxed for 6 h; cooled to 20°C; filtered through Kieselguhr; catalyst evapd.; chromy.; evapd.; crystd. from benzene/pertoleum ether at -18°C;
参考文献
Hudecek, Milan; Toma, Stefan
Journal of Organometallic Chemistry, 1991 , vol. 406, # 1+2 p. 147 - 151
反应条件
methanol; carbon monoxide; sodium acetate; bis-triphenylphosphine-palladium(II) chloride in neat (no solvent) High Pressure; stainless steel, Teflon-coated autoclave, PPh3 presence (catalytic system), 25 bar CO, 170°C, 20-70 h; GLC; free organic byproducts also formed;
参考文献
Mutin, Robert; Lucas, Christine; Thivolle-Cazat, Jean; Dufaud, Veronique; Dany, Fabienne; Basset, Jean Marie
Journal of the Chemical Society, Chemical Communications, 1988 , # 13 p. 896 - 898
反应条件
methanol; triethyl amine in chlorobenzene (Ar), Et3N added dropwise to stirred soln. at room temp.; GLC;
参考文献
Dufaud, Veronique; Thivolle-Cazat, Jean; Basset, Jean-Marie; Mathieu, Rene; Jaud, Joel; Waissermann, Jaqueline
Organometallics, 1991 , vol. 10, p. 4005 - 4015
反应条件
in neat (no solvent) in bomb tube at 150-165°C;;
参考文献
Klopman; Noack
Inorganic Chemistry, 1968 , vol. 7, p. 579,580,581
反应条件
methanol in methanol; sulfuric acid
参考文献
Nicholls, B.; Whiting, M. C.
Journal of the Chemical Society, 1959 , p. 551 - 556
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Gmelin Handbook: Cr: Org.Verb., 1.6.1.2.1.3, page 200 - 211
反应条件
methanol; triethyl amine in chlorobenzene (Ar), Et3N added dropwise to stirred soln. at room temp.; GLC;
参考文献
Dufaud, Veronique; Thivolle-Cazat, Jean; Basset, Jean-Marie; Mathieu, Rene; Jaud, Joel; Waissermann, Jaqueline
Organometallics, 1991 , vol. 10, p. 4005 - 4015
反应条件
in tetrahydrofuran refluxing in THF for 62 h at 130°C; extn. of solvent, chromy. (SiO2, hexane/benzene/ether (5:1:1)), IR, (1)H-NMR;
参考文献
Matarasso-Tchiroukhine, Elisabeth; Jaouen, Gerard
Canadian Journal of Chemistry, 1988 , vol. 66, p. 2157 - 2160
反应条件
in tetrahydrofuran byproducts: CO; Irradiation (UV/VIS); irradn. of a soln. of arene and Cr(CO)6 in degassed THF for 40 h at room temp. under N2; removal of THF under reduced pressure, dissoln. of residue in pentane/EtOAc (9/1), chromy. on silica column., elution, evapn. under reduced pressure, recrystn. from pentane;
参考文献
Kostermans, G. B. M.; Bobeldijk, M.; Kwakman, P. J.; Wolf, W. H. de; Bickelhaupt, F.
Journal of Organometallic Chemistry, 1989 , vol. 363, p. 291 - 296
反应条件
in anhydrous butyl ether treatment of tris(acetonitrile)tricarbonylmetal complex with benzene deriv. in n-Bu2O at 50°C in vac.; chromy. (silica gel), recrystn. from hexane/benzene or toluene;
参考文献
Mueller, Joern; Luedemann, Frerk
Journal of Organometallic Chemistry, 1981 , vol. 204, # 3 p. 361 - 376
反应条件
in not given N2-atmosphere;
参考文献
Lotz, Simon; Schindehutte, Minet; Dyk, Marthime M. van; Dillen, Jan L. M.; Rooyen, Petrus H. van
Journal of Organometallic Chemistry, 1985 , vol. 295, p. 51 - 62
