in carbon disulfide
under N2, dropwise addn. of a Br2/CS2 soln. to a vigorously stirred soln. of P4/CS2 reaction of P4 with ICl (molar ratio (1.75:1.5), further Products: PCl3, PCl2I, PClI2, PI3; not isolated, identified by 31P-NMR spectroscopy;
参考文献
Tattershall, Bruce W.; Kendall, Nigel L.
Polyhedron, 1994 , vol. 13, p. 1517 - 1522
Gmelin Handbook: F: PerFHalOrg.3, 1.9, page 70 - 123
Full Text Show Details
Bennet, F. W.; Emeleus, H. J.; Haszeldine, R. N.
Journal of the Chemical Society, 1953 , p. 1565 - 1571
in water-d2; toluene
Kinetics; Ar, P4 (or soln. of P4 in toluene) added in small portions, heated to 60-60°C, stirred for 0.5-4 h; not isolated, detected by NMR;
参考文献
Akbayeva, Dina N.; Faisova, Farida Kh.; Abdreimova, Rumia R.; Peruzzini, Maurizio
Journal of Molecular Catalysis A: Chemical, 2007 , vol. 267, # 1-2 p. 181 - 193
in water-d2; toluene
Kinetics; Ar, P4 (or soln. of P4 in toluene) added in small portions, heated to 25-60°C, stirred for 0.5-4 h; not isolated, detected by NMR;
参考文献
Akbayeva, Dina N.; Faisova, Farida Kh.; Abdreimova, Rumia R.; Peruzzini, Maurizio
Journal of Molecular Catalysis A: Chemical, 2007 , vol. 267, # 1-2 p. 181 - 193
