(E)-3-对甲苯丙烯酸丁酯合成路线 （共 28 条）
反应条件
[Rh(OH)(cycloocta-1,5-diene)]2 in tetrahydrofuran; water
T=70°C; 24 h;
参考文献
Mori; Danda; Fujii; Hirabayashi; Osakada
Journal of the American Chemical Society, 2001 , vol. 123, # 43 p. 10774 - 10775
反应条件
[Ir2(OMe)2(1,5-cyclooctadiene)2]; tetrabutyl ammonium fluoride in water; toluene
T=70°C; Mizoroki-Heck-type addition/elimination react.; 24 h; Title compound not separated from byproducts;
参考文献
Koike, Tooru; Du, Xiaoli; Sanada, Tomoyuki; Danda, Yasuaki; Mori, Atsunori
Angewandte Chemie - International Edition, 2003 , vol. 42, # 1 p. 89 - 92
反应条件
lithium chloride; [Rh(C2H4)2Cl]2 in xylene
Mizoroki-Heck reaction; 5 h; Heating; Title compound not separated from byproducts;
参考文献
Sugihara, Toru; Satoh, Tetsuya; Miura, Masahiro; Nomura, Masakatsu
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1765 - 1772
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; copper (II) acetate monohydrate; trichloroacetic acid
T=120°C; 22 h; regioselective reaction;
参考文献
Zheng, Lu; Wang, Jianhui
Chemistry - A European Journal, 2012 , vol. 18, # 31 p. 9699 - 9704
反应条件
1.1: BuLi / diethyl ether / 1 h / -78 °C
1.2: 73 percent / diethyl ether / 13 h / 20 °C
2.1: 54 percent / Cu(OAc)2; LiOAc / Pd(OAc)2 / dimethylformamide / 24 h / 100 °C
View Scheme
参考文献
Hirabayashi, Kazunori; Ando, Jun-Ichi; Kawashima, Jun; Nishihara, Yasushi; Mori, Atsunori; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 6 p. 1409 - 1417
反应条件
caesium carbonate; palladium diacetate in water; N,N-dimethyl-formamide
T=120°C; Mizoroki-Heck reaction; 0.5 h;
参考文献
Shibata, Kana; Satoh, Tetsuya; Miura, Masahiro
Organic Letters, 2005 , vol. 7, # 9 p. 1781 - 1783
反应条件
triethylamine in N,N-dimethyl-formamide
T=140°C; Heck Reaction; 24 h; Green chemistry;
参考文献
Basu, Basudeb; Paul, Susmita
Applied Organometallic Chemistry, 2013 , vol. 27, # 10 p. 588 - 594
反应条件
1: sodium sulfite / water / 5 h / 70 - 80 °C
2: palladium diacetate; copper (II) acetate monohydrate / 1,4-dioxane / 24 h / 100 °C
View Scheme
参考文献
Wang, Guan-Wu; Miao, Tao
Chemistry - A European Journal, 2011 , vol. 17, # 21 p. 5787 - 5790
