PhCH2Pd(PPh3)2Cl in 1,2-dichloro-ethane T=20°C; 0.0833333 h;

PhCH2Pd(PPh3)2Cl in 1,2-dichloro-ethane T=20°C; 0.0833333 h;

bis-triphenylphosphine-palladium(II) chloride in 1,2-dichloro-ethane byproducts: PhC(O)CCPh; under Ar; mixt. of Sb compd., PhC(O)Cl and PdCl2(PPh3)2 (molar ratio 1:1:0.03) in 1,2-dichloroethane stirred at room temp. for 1 h; diluted with ether; satd. aq. NaHCO3 added; stirred at room temp. for 10min; aq. layer extd. with ether; org. layers combined; washed with brin e; dried (anhyd. MgSO4); solvent removed in vac.; sepd. by column chromy. (silica gel, hexane-ether 1:1);

PhCH2Pd(PPh3)2Cl in 1,2-dichloro-ethane T=20°C; 0.0833333 h;

bis-triphenylphosphine-palladium(II) chloride in 1,2-dichloro-ethane T=20°C; 1 h;

PhCH2Pd(PPh3)2Cl in 1,2-dichloro-ethane T=20°C; 0.0833333 h;

PhCH2Pd(PPh3)2Cl in 1,2-dichloro-ethane T=20°C; 0.333333 h;

PhCH2Pd(PPh3)2Cl in 1,2-dichloro-ethane T=20°C; 0.0833333 h;