1279123-63-5合成路线 （共 36 条）
反应条件
treatment of satd. soln. of Bi-salt with K-salt, according t: A. A. Opalovskii, T. F. Gudimovich et al., Zhur. Obshch. Khim. 47 (1977) 528; washing with acetic acid soln.; X-ray diffraction, IR spectroscopy; elem. anal.;
参考文献
Opalovskii, A. A.; Gudimovich, T. F.; Sokhranenko, G. P.; Popov, V. P.; Kolodezev, A. B.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1978 , vol. 23, p. 444 - 446
Zhurnal Neorganicheskoi Khimii, 1978 , vol. 23, p. 804 - 808
反应条件
PdCl(C6H4C6H4NH2)(Cy2PC6H4-2-C6H2-2',4',6'-i-Pr3); Cy2PC6H4-2-C6H2-2',4',6'-i-Pr3; K acetate in ethanol aryl chloride reacted with B2(OH)4 in EtOH in presence of catalyst (Pt-complex - ligand) and K acetate at 80°C for 1 h; subjected to aq. workup; treated with KHF2; purified by Soxlet extn.;
参考文献
Molander, Gary A.; Trice, Sarah L. J.; Kennedy, Steven M.; Dreher, Spencer D.; Tudge, Matthew T.
Journal of the American Chemical Society, 2012 , vol. 134, # 28 p. 11667 - 11673
反应条件
in neat (no solvent) addn. of small portions dry KHF2 to H2SO4 (containing 60percent SO3) in cooled platinum vessel;; heating (100°C/evapn. of exceeding HF/SO3); distillation; fractionating;;
参考文献
Meyer, J.; Schramm, G.
Z. Anorg. Chem., 1932 , vol. 206, p. 24 - 30
反应条件
in neat (no solvent)
参考文献
Gmelin Handbook: S: MVol.B3, 97, page 1739 - 1740
反应条件
in acetonitrile byproducts: HCl, SiF4; gently refluxing KHF2 suspension; addn. of SO2Cl2 soln. with stirring during 1h; refluxing, 1h; condensing into trap at liq. nitrogen temp.; distn., -100°C; distn., -50°C; separation of SO2ClF; addn. of HI to distillate; passing through KMnO4 soln.; drying over P2O5; storage in a glass globe; elem. anal.;
参考文献
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, , vol. 20, p. 777 - 779
反应条件
PdCl(C6H4C6H4NH2)(Cy2PC6H4-2-C6H2-2',4',6'-i-Pr3); Cy2PC6H4-2-C6H2-2',4',6'-i-Pr3; K acetate in ethanol aryl bromide reacted with B2(OH)4 in EtOH in presence of catalyst (Pt-complex - ligand) and K acetate at 80°C for 3 h; subjected to aq. workup; treated with KHF2; purified by Soxlet extn.;
参考文献
Molander, Gary A.; Trice, Sarah L. J.; Kennedy, Steven M.; Dreher, Spencer D.; Tudge, Matthew T.
Journal of the American Chemical Society, 2012 , vol. 134, # 28 p. 11667 - 11673
反应条件
in hydrogenchloride pptn. from 7E-3 molar Sc(3+)-soln. in aq. HCl, 90-95°C, pH=2;; no quantitative react. in presence of Zr(4+), Ti(4+), Al(3+) or Fe(3+);,;
参考文献
Favorskaya, L. V.; Presnetsova, V. A.
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1970 , vol. 43, p. 999 - 1002
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1970 , vol. 43, p. 985 - 9990
Full Text Show Details
Gmelin Handbook: Sc: MVol.C3, 6.2.5.1.1.1, page 138 - 139
反应条件
in acetonitrile byproducts: KCl, HCl; a mixt. of KHF2 and POCl3 (equal amts.) in MeCN was stirred for 24 h at room temp.;; the solvent was distd. off, the solid residue agitated with EtOH, KPF6 pptd. by addn. of ether; after filtration, the filtrate was evapd. to yield KPO2F2; elem. anal.;
参考文献
Kalbandkeri, R. G.; Padma, D. K.; Vasudeva Murthy, A. R.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1984 , vol. 23, p. 990 - 991
反应条件
in acetonitrile byproducts: KBr, HBr; a mixt. of KHF2 and POBr3 (equal amts.) in MeCN was stirred for 24 h at room temp.;; the solvent was distd. off, the solid residue agitated with EtOH, KPF6 pptd. by addn. of ether; after filtration, the filtrate was evapd. to yield KPO2F2; elem. anal.;
参考文献
Kalbandkeri, R. G.; Padma, D. K.; Vasudeva Murthy, A. R.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1984 , vol. 23, p. 990 - 991
反应条件
HNO3 in hydrogen fluoride aq. HF; dissoving of NB in 60-percent aq. HF, addition of HNO3, precipitating with solution of KH2F in 60-percent aq. HF;; washing with aq. HF, recrystallization from aq. HF, drying;;
参考文献
Savchenko, G. S.; Tananaev, I. V.
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1946 , vol. 19, p. 1093 - 1106
C. A., 1947 , p. 4733
Full Text Show Details
Gmelin Handbook: Nb: MVol.B4, 9.3.1, page 201 - 202
