5beta-孕甾烷-3,20-二酮合成路线 (共 54 条)
反应条件
recombinant human aldo-keto reductase 1C1; NADPH in methanol T=37°C; pH=7; 0.5 h; aq. phosphate bufferEnzymatic reaction; stereospecific reaction;
参考文献
Jin, Yi; Mesaros, A. Clementina; Blair, Ian A.; Penning, Trevor M.
Biochemical Journal, 2011 , vol. 437, # 1 p. 53 - 61
参考文献
Butenandt; Mueller
Chemische Berichte, 1938 , vol. 71, p. 191,196
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Marker; Kamm; Wittle
Journal of the American Chemical Society, 1937 , vol. 59, p. 1841
参考文献
Butenandt; Mueller
Chemische Berichte, 1938 , vol. 71, p. 191,196
Full Text Show Details
Marker; Kamm; Wittle
Journal of the American Chemical Society, 1937 , vol. 59, p. 1841
反应条件
lt;(-)-(2S,3S)-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (diop)gt;Rh(solvent)Cl; (Ph)2SiH2 further with (+)-diop; Product distribution;
参考文献
Goendoes, Gyoergy; Orr, James C.
Journal of the Chemical Society, Chemical Communications, 1982 , # 21 p. 1238 - 1239