二(甲基环戊二烯基)二氯化钛合成路线 （共 14 条）
反应条件
in diethyl ether methylcyclopentadienyllithium suspn. added dropwise to stirred complex soln. at 0°C under Ar, allowed to warm to room temp., stirred for30 min; concd. (vac.), aq. HCl added, solids filtered, washed with aq. HCl, with cold ether, dried, fractionally crystd. (hot toluene);
参考文献
Ott, Kevin C.; deBoer, E. J. M.; Grubbs, Robert H.
Organometallics, 1984 , vol. 3, p. 223 - 230
反应条件
in not given NaC5H4Me reacted with TiCl4(THF)2;
参考文献
Gomez-Ruiz, Santiago; Gallego, Beatriz; Zizak, Zeljko; Hey-Hawkins, Evamarie; Juranic, Zorica D.; Kaluderovic, Goran N.
Polyhedron, 2010 , vol. 29, # 1 p. 354 - 360
反应条件
in carbon disulfide byproducts: bis(trichloromethyl)tetraasulfane; addn. of CCl3SCl to soln. of Ti complex with stirring, (20°C, 12-15 h); filtration of (C5H4(CH3))2TiCl2;
参考文献
Steudel, Ralf; Pridoehl, Markus; Buschmann, Juergen; Luger, Peter
Chemische Berichte, 1995 , vol. 128, # 7 p. 725 - 728
反应条件
in dichloromethane
refluxing of (CH3C5H4)2TiCl2 in CH2Cl2 with phenylhydrazinium phenyldithiocarbazate for 8-10 h; hot filtration;; concn. in vac.; addn. of petroleum ether (60-80°C); storing overnight; crystallization; filtration; drying at 50°C for 2 h in vac.; elem. anal.;;
参考文献
Kaushik, N. K.; Bhushan, B.; Sodhi, G. S.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1981 , vol. 20, # 6 p. 625 - 626
