双(1,5-环辛二烯)镍(0)合成路线 （共 74 条）
反应条件
under Ar; 50°C, 36 h;
参考文献
Benn, R.; Buessemeier, B.; Holle, S.; Jolly, P. W.; Mynott, R.; et all.
Journal of Organometallic Chemistry, 1985 , vol. 279, p. 63 - 86
反应条件
in diethyl ether Irradiation (UV/VIS); iC3H7MgBr excess, water free NiCl2, 8 h;
参考文献
Mueller, J.; Goeser, P.
Angewandte Chemie, 1967 , vol. 79, p. 380 - 381
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Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88
反应条件
in benzene byproducts: Al(C5H7O2)3; 0°C; molar ratio of Ni(C5H7O2)2:1,5-cyclooctadiene:(C2H5)2AlOC2H5= 1:2.5:2.3; 2.5h; solvolyse with ethanol and 2nHCl below 5°C; distn. in high vacuum at 40-50°C; cooling and crystn.;
参考文献
Diss. Aachen T. H. 1961
反应条件
in not given byproducts: ethene;
参考文献
Chemische Berichte, , vol. 123, p. 1267 - 1274
参考文献
Angewandte Chemie, , vol. 99, p. 953 - 954
反应条件
in toluene-d8 byproducts: P(C6H11)3; Ni complex in soln. of toluene-d8 gradually decompd. at room temp. over 60 h; monitored by NMR spectra;
参考文献
Organometallics, , vol. 29, # 11 p. 2386 - 2389
反应条件
in tetrahydrofuran byproducts: ethylene; -30°C;
参考文献
Kaschube, Wilfried; Poerschke, Klaus R.; Bonrath, Werner; Krueger, Carl; Wilke, Guenther
Angewandte Chemie, 1989 , vol. 101, p. 790 - 792
参考文献
Organometallics, , vol. 1, p. 401 - 402
参考文献
Journal of the Chemical Society, Chemical Communications, , p. 1098 - 1099
Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88
反应条件
between -5 and -2°C; washing with cold benzene and ether or recrystn. from benzene at max. 60-70°C;
参考文献
Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88
