双(1,5-环辛二烯)镍(0)合成路线 （共 74 条）
反应条件
byproducts: Ni; between -5 and -2°C; washing with cold benzene and ether or recrystn. from benzene at max. 60-70°C;
参考文献
Bogdanovic,B. et al.
Justus Liebigs Annalen der Chemie, 1966 , vol. 699, p. 1 - 23
反应条件
in diethyl ether under N2 or argon or under vac., soln. of org. compd. added to Ni(cod)2(1/1 mol ratio) at -78°C, stirred at 10°C for 2 h; cooled to -78°C, solvent evapd. under vac., warmed to 0°C, product distd., distn. residue identified as Ni-acetate; detn. by IR, NMR spect.;
参考文献
Yamamoto, Takakazu; Ishizu, Junichi; Yamamoto, Akio
Journal of the American Chemical Society, 1981 , vol. 103, # 23 p. 6863 - 6869
反应条件
triphenylphosphine in neat (no solvent) byproducts: 1,5-cyclooctadiene; under N2 or argon or under vac., excess of org. compd. added to mixt. of Ni(cod)2 and PPh3 stirred at 47°C for 5 h; react. time depends on the presence of PPh3, without PPh3 is 96 h.; detn. by IR and NMR;
参考文献
Yamamoto, Takakazu; Ishizu, Junichi; Yamamoto, Akio
Journal of the American Chemical Society, 1981 , vol. 103, # 23 p. 6863 - 6869
反应条件
in toluene under Ar, Ni(COD)2 and Ph2PCH2COOH dissolved in toluene, kept 1 h at room temp., solvent distilled off at E-2 Torr, residue dissolved in mixt. of toluene and n-hexene, cooled to -30°C, filtered off, added n-hexane and n-octane, kept several d; recrystd. from mixt. of toluene, hexane, and octane;
参考文献
Peuckert, Marcell; Keim, Wilhelm
Organometallics, 1983 , vol. 2, p. 594 - 597
反应条件
triphenylphosphine in tetrahydrofuran under N2 or argon or under vac., soln. of org. compd. (8.7 mol) added to mixt. of Ni(cod)2 and PPh3 (1.0/2.1 mol ratio), stirred at 30°Cfor 2 d; detn. by IR and NMR;
参考文献
Journal of the American Chemical Society, , vol. 103, # 23 p. 6863 - 6869
反应条件
triphenylphosphine in tetrahydrofuran under N2 or argon or under vac., soln. of org. compd. (3.8 mol) added to mixt. of Ni(cod)2 and PPh3 (1.0/2.2 mol ratio), stirred at 30°Cfor 2 d; detn. by IR and NMR;
参考文献
Journal of the American Chemical Society, , vol. 103, # 23 p. 6863 - 6869
反应条件
in acetonitrile under Ar atm.; Fe and Ni complexes dissolved in MeCN; soln. stirred at room temp. for 10 min; monitored by IR spectroscopy; solvent removed (vac.); residue washed (hexane); residue dissolved in CH2Cl2; filtered;
参考文献
Saha, Sumit; Zhu, Lei; Captain, Burjor
Inorganic Chemistry, 2010 , vol. 49, # 7 p. 3465 - 3472
反应条件
triphenylphosphine in further solvent(s) Kinetics; (N2 or Ar or vac.), EtCOOPh-CN added to Ni(cod)2 and PPh3 (PPh3/Ni = 3)in acetophenone, mixture stirred at 70°C for 27 h; GLC;
参考文献
Journal of the American Chemical Society, , vol. 102, # 11 p. 3758 - 3764
反应条件
triphenyl phosphine; carbon monoxide in not given N2 atmosphere;;
参考文献
Polyhedron, , vol. 8, p. 1351 - 1356
反应条件
triphenylphosphine in neat (no solvent) byproducts: CO2, C2H4; ester added to Schlenk tube contg. Ni(cod)2 and PPh3, stirred at 10°C for 12 h; evapn. in vac.; GLC anal.;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 55, # 2 p. 623 - 624
