in sodium hydroxide
Kinetics; byproducts: H2O; dispersed Se dissolved in thermostatically controlled glass cell with apropeller mixer; NaOH concn. in the range 1.0-5.0; temp. from 25 to 85°C; oxygen passed above the soln. (1 l/min); volumetry;
参考文献
Ugorets, M. Z.; Sagindykova, Z. B.; Semina, O. I.
Journal of Applied Chemistry USSR (English Translation), 1981 , vol. 54, p. 281 - 283
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1981 , vol. 54, p. 394 - 396
cetyltrimethylammonium bromide; hydrazine hydrate; glucose in sodium hydroxide
aq. NaOH; High Pressure; CuCl2 (0.8 mmol) in 3 M NaOH, CTAB (6 mmol), mixt. stirred vigirously for 30 min at 50°C, stored at room temp. for 1 h, various product ratio for various conditions; filtered off, washed (ethanol, water); XRD, SEM, TEM;
hydrazine monohydrate; gelatin in water
mixed N2H2*H2O and gelatin soln. added to CuO suspn. at 323 K, pH=8.5 adjusted by NaOH soln., or at 353 K and pH=7.6, soln. stirred at N2 bubbling for 2 h;
参考文献
Engels, Volker; Benaskar, Faysal; Jefferson, David A.; Johnson, Brian F. G.; Wheatley, Andrew E. H.
Dalton Transactions, 2010 , vol. 39, # 28 p. 6496 - 6502
in water
byproducts: sulfide; finely divided (dust fineness) powder of S4N3Cl is moistened by a small amount of water, dissolved in cold aq. 2.5n NaOH and brought to boil in a flow of N2;; Product contains 50percent thiosulfate, 40percent sulfite, and 10percent sulfide;;
参考文献
Meuwsen, A.; Jakob, O.
Z. Anorg. Chem., 1950 , vol. 263, p. 200 - 212
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Gmelin Handbook: S: MVol.B3, 155, page 1858 - 1860
in tetrachloromethane; water
hydrolysis of soln. (in CCl4) by aq. NaOH (10 min);;
参考文献
Rao, M. R. A.
Proceedings - Indian Academy of Sciences, Section A, 1940 , vol. 11, p. 185 - 200
Brit. C.A., 1940 , p. I 296
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Gmelin Handbook: S: MVol.B3, 124, page 1796 - 1798
