air or O2;; catalyst: alumina in neat (no solvent)
byproducts: CO, CO2; oxidn. with O2 or air (react. is followed by IR);;
参考文献
Gmelin Handbook: Ni: Org.Verb.1, 1.1.5.4.1.3.4, page 226 - 228
Full Text Show Details
Parkyns, N. D.
Proc. 3rd Intern. Congr. Catalysis, Amsterdam 1964 (1965), S. 914/27
in neat (no solvent)
byproducts: H2, H2O, CO; static air atmosphere; heating up to 1273 K (heating rate 1 - 10 K/min); reaction followed by X-ray diffraction;
参考文献
Elmasry; Gaber; Khater
Journal of thermal analysis, 1996 , vol. 47, # 3 p. 757 - 763
Chakravarty, K. M.; Litkenhous, E. E.
Industrial and Engineering Chemistry, 1939 , vol. 31, p. 1059 - 1060
Full Text Show Details
Schneider, J.
Z. Kompr. Fluessige Gase, 1940 , vol. 35, p. 7 - 8
Dimethylglyoxime; nitric acid in ethanol; ammonia; water
byproducts: NH4F; addn. of aq. NH4OH to Ni(PF3)4, cooling with liquid nitrogen, mixing for 15 min, addn. of HNO3, adjusting pH to 7-8 by addn. of NH4OH, heating to 80°C, pptg. by addn. of alcoholicammoniacal soln. of dimethylglyoxime; filtn., heating at 850°C;
参考文献
Vereshchagin, Yu. I.; Voinova, S. E.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1983 , vol. 28, p. 147 - 148
Zhurnal Neorganicheskoi Khimii, 1983 , vol. 28, p. 263 - 264
air in neat (no solvent)
byproducts: H2O, CO2; other Radiation; sample heating at 10 K/min in air up to 480°C under simultaneousγ-rays irradiation at 1E+3 to 1E+6 Gy using Co-60-γ-ray sou rce; TG, DTG;
参考文献
Abd El-Wahab; Mahfouz
Thermochimica Acta, 1996 , vol. 274, # 1-2 p. 281 - 287
triethyl orthoformate; O2 in acetonitrile
vac. line and Schlenk technique; soln. of Ni compd. in CH3CN was added dropwise to soln. of ligand and triethyl orthoformate in CH3CN; soln. waskept in presence of O2 for 3 d; filtered; solvent evapd.; elem. anal.;
