3-甲基-CBS-氧硼啶合成路线 （共 731 条）
反应条件
1: 4-methoxyphenyl magnesium bromide With bismuth(III) chloride 2: 2-benzoyl-5-bromothiophene With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
triphenylphosphine; Pd bipyridyl anchored nanosized mesoporous silica MCM-41 in tetrahydrofuran Kumada-Corriu reaction; 24 h; Heating;
参考文献
Tetrahedron, , vol. 63, # 20 p. 4304 - 4309
反应条件
1: 4-methoxyphenyl magnesium bromide With bismuth(III) chloride 2: 5-Bromothiophene-2-carboxaldehyde With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
1: 4-methoxyphenyl magnesium bromide With bismuth(III) chloride 2: (5-iodo-2-thienyl)(phenyl)methanone With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide T=90°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
[(P{(C6H11)3})2Pd(Cl)2] in tetrahydrofuran T=0 - 70°C; Inert atmosphere;
参考文献
Konishi, Hideyuki; Itoh, Tatsuya; Manabe, Kei
Chemical and Pharmaceutical Bulletin, 2010 , vol. 58, # 9 p. 1255 - 1258
反应条件
[(P{(C6H11)3})2Pd(Cl)2] in tetrahydrofuran T=0 - 50°C; Inert atmosphere;
参考文献
Konishi, Hideyuki; Itoh, Tatsuya; Manabe, Kei
Chemical and Pharmaceutical Bulletin, 2010 , vol. 58, # 9 p. 1255 - 1258
反应条件
dilithium tetrachlorocuprate in tetrahydrofuran 12 h; Ambient temperature;
参考文献
Kadkhodayan, Miryam; Singleton, Terry; Heldrich, F. J.
Synthetic Communications, 1984 , vol. 14, # 8 p. 707 - 712
反应条件
diisobutylaluminium hydride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran 36 h; Ambient temperaturefurther temperature and reaction time; Product distribution;
参考文献
Tetrahedron Letters, , vol. 27, # 49 p. 6013 - 6016
反应条件
FeCl(THF)L1 in diethyl ether T=20°C; 0.5 h; Schlenk techniqueInert atmosphere; Catalytic behavior;
参考文献
UNIVERSITY OF PRINCE EDWARD ISLAND; GENESIS GROUP INC.; SHAVER, Michael, P.; KOZAK, Christopher, M.
Patent: WO2013/53046 A1, 2013 ;
Location in patent: Paragraph 00282; 00283; 00285 ;
反应条件
FeCl(THF)L1 in diethyl ether T=20°C; 0.5 h; Schlenk techniqueInert atmosphere; Catalytic behavior;
参考文献
UNIVERSITY OF PRINCE EDWARD ISLAND; GENESIS GROUP INC.; SHAVER, Michael, P.; KOZAK, Christopher, M.
Patent: WO2013/53046 A1, 2013 ;
Location in patent: Paragraph 00282; 00283; 00286 ;
