2,3,4,6-四-O-乙酰基-1-溴-Alpha-D-甘露糖合成路线 （共 50 条）
反应条件
1: 18 percent / HgBr2 / CH2Cl2 / 24 h 2: 1.) H2, 2.) NaOMe / 1.) Pd/C / 1.) EtOH, HOAc, overnight, 2.) MeOH, room temperature, overnight View Scheme
参考文献
Madiyalakan, Ragupathy; Chowdhary, Manjit S.; Rana, Surjit S.; Matta, Khushi L.
Carbohydrate Research, 1986 , vol. 152, p. 183 - 194
反应条件
cesium fluoride in acetonitrile 24 h;
参考文献
Jain, Sudha; Suryawanshi, S. N.; Misra, Shalini; Bhakuni, D. S.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1988 , vol. 27, # 9 p. 866
反应条件
1: With 2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in toluene T=85°C; 0.5 h; 2: With sodium methylate in methanol 2 h;
参考文献
Dubber, Michael; Lindhorst, Thisbe K.
Journal of Carbohydrate Chemistry, 2001 , vol. 20, # 7-8 p. 755 - 760
反应条件
lithium aluminium tetrahydride; diethyl ether
参考文献
Ness et al.
Journal of the American Chemical Society, 1950 , vol. 72, p. 4547
反应条件
ethanol; trimethylamine; benzene
参考文献
Chen, Liqun; Tan, Zhongping
Tetrahedron Letters, 2013 , vol. 54, # 17 p. 2190 - 2193
反应条件
sodium acetate in water T=20 - 30°C;
参考文献
Sasaki, Eita; Ogasawara, Yasushi; Liu, Hung-Wen
Journal of the American Chemical Society, 2010 , vol. 132, # 21 p. 7405 - 7417
参考文献
Bonner
Journal of the American Chemical Society, 1958 , vol. 80, p. 3372,3378
Journal of the American Chemical Society, 1959 , vol. 81, p. 5171,5172, 5176
反应条件
indium(III) chloride; indium; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; water T=20°C; 8 h;
参考文献
Cho, Sangwon; Kang, Soyeon; Keum, Gyochang; Kang, Soon Bang; Han, So-Yeop; Kim, Youseung
Journal of Organic Chemistry, 2003 , vol. 68, # 1 p. 180 - 182
反应条件
anhydrous iron chloride; para-fluorostyrene in tetrahydrofuran T=0 - 20°C; 1 h; diastereoselective reaction;
参考文献
Nicolas, Lionel; Angibaud, Patrick; Stansfield, Ian; Bonnet, Pascal; Meerpoel, Lieven; Reymond, Sebastien; Cossy, Janine
Angewandte Chemie - International Edition, 2012 , vol. 51, # 44 p. 11101 - 11104
Angew. Chem., 2012 , vol. 124, # 44 p. 11263 - 11266,4
反应条件
anhydrous iron chloride; jackiePhos in tetrahydrofuran T=20°C; 1 h; Reagent/catalystSolventTemperature; diastereoselective reaction;
参考文献
Nicolas, Lionel; Angibaud, Patrick; Stansfield, Ian; Bonnet, Pascal; Meerpoel, Lieven; Reymond, Sebastien; Cossy, Janine
Angewandte Chemie - International Edition, 2012 , vol. 51, # 44 p. 11101 - 11104
Angew. Chem., 2012 , vol. 124, # 44 p. 11263 - 11266,4
