in ethanol a blue oxide formed, too which decompn. in air quickly;
参考文献
Forcher, V.
Ber. Wien. Akad., 1861 , vol. 44 II, p. 163
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Forcher, V.
Journal fuer Praktische Chemie (Leipzig), 1862 , vol. 86, p. 232
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Gmelin Handbook: W: MVol., 2.6, page 158 - 178
in dichloromethane
mixt. of WCl6 and CH2Cl2 under N2 was stirred at room temp., N2 was replaced by NO for 30 min, NO was flushed out of system, mixt. was refluxedunder N2 for 3.5 h to removed ClNO; filtered, washed with CH2Cl2, dried under vac. at ambient temp.; elem. anal.;
参考文献
Hunter, Allen D.; Legzdins, Peter
Inorganic Chemistry, 1984 , vol. 23, p. 4198 - 4204
in dichloromethane
mixt. of WCl6 and CH2Cl2 under N2 was stirred at room temp., N2 was replaced by NO for 17 min, NO was flushed out of system, mixt. was refluxedunder N2 for 3.5 h to removed ClNO; filtered, washed with CH2Cl2, dried under vac. at ambient temp.; elem. anal.;
参考文献
Hunter, Allen D.; Legzdins, Peter
Inorganic Chemistry, 1984 , vol. 23, p. 4198 - 4204
in neat (no solvent)
Kinetics; reaction of solid WCl6 with gaseous NO2 kinetically studied at 25-200°C;
参考文献
Zelikman, A. N.; Leonova, L. M.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1984 , vol. 29, p. 1578 - 1580
Zhurnal Neorganicheskoi Khimii, 1984 , vol. 29, p. 2754 - 2756
in neat (no solvent)
under exclusion of moisture, WCl6 and excess Cl3CNO2 refluxed; filtered; dried under vac. (2 h); elem. anal.;
参考文献
Prinz, H.; Dehnicke, K.; Mueller, U.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1982 , vol. 488, p. 49 - 59
→
反应条件
in neat (no solvent)
react. of WO3 and WCl6 in stoich. amts. in sealed ampoule at 100°C according to P. C. Crouch et al., J. Inorg. Nucl. Chem., 1970, 32, 329; treatment of oxide sublimate with ether at 20°C, WO2Cl2 residue (drying in vac.); evapn. of decanted soln. gives WOCl4 and WOCl4*(C2H5)2O which dissolves in a vac. at 57°C to give WOCl4; elem. anal.;
参考文献
Kucheiko, S. I.; Turova, N. Ya.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1985 , vol. 30, p. 756 - 756
Zhurnal Neorganicheskoi Khimii, 1985 , vol. 30, p. 1327 - 1328
in anhydrous butyl ether; benzene
Addn. of organomagnesium soln. to metal salt soln. in benzene.; GC after 2-5h.;
参考文献
Kostitsyna, N. N.; Oreshkin, I. A.; Dolgoplosk, B. A.
Doklady Physical Chemistry (Translation of the physical chemistry section of Doklady Akademii Nauk), 1986 , vol. 286 - 288, p. 10 - 12
Doklady Akademii Nauk SSSR, 1986 , vol. 286, p. 132 - 134
