in neat (no solvent) byproducts: H2, S(CH3)2; react. in a round-bottom flask under N2, addn. of the alcohol to the borane complex at room temp. (stirred), refluxed (according to Brown, Krishnamurthy, J.Org.Chem. 1978, 43, 2731; with a slight modification); distn. from a small piece of K metal;
参考文献
Brown, Herbert C.; Cha, Jin Soon; Nazer, Behrooz
Inorganic Chemistry, 1984 , vol. 23, p. 2929 - 2931
carbon monoxide; acetone in tetrahydrofuran byproducts: S(CH3)2; a soln. of BH3*S(CH3)2 flushed with CO; a soln. of catalyst added, stirred rapidly and maintained at 25°C for 12-16 h; acetone added; evapd.;
参考文献
Brown, Herbert C.; Cole, Thomas E.
Organometallics, 1985 , vol. 4, p. 816 - 821
