copper(l) iodide in diethyl ether hydrogermane mixed with 4 equiv. of CuCl2 and CuI in ether under room temp. for 8 h; solvent evapd., distilled under reduced pressure;
in cyclohexane Kinetics; byproducts: CCl3CCl3; Irradiation (UV/VIS); photolysis of Ge-compd. in cyclohexane in the presence of CCl4 at 245 nm at room temp. for 30 min with a 110 W low pressure Hg arc lamp;
in chloroform byproducts: SO2; under N2 or Ar; soln. of SOCl2 in CHCl3 added in portions to soln. of Ge-compd. kept at 0°C, warmed to room temp., evapn. of solvent under vac.; identified by NMR;
参考文献
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 10, p. 515 - 530
in benzene byproducts: HCl; heating in a sealed tube at 80 ° C for 12 h,; concn. (reduced pressure), anal. (IR, H-NMR, MS); 13percent starting germane;
参考文献
Journal of Organometallic Chemistry, , vol. 339, p. 51 - 60
