byproducts: CF3SH, S, CsF*HF; warming to 25°C in the presence of excess CsF;
参考文献
Burton,C.A.; Shreeve,J.M.
Journal of the American Chemical Society, 1976 , vol. 98, p. 6545 - 6547
Full Text View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.5, page 172 - 209
methyl iodide in further solvent(s) byproducts: CsI; (Ar); standard Schlenk technique; toluene (1 equiv.), MeI (2 equiv.) and CsF (1.4 equiv.) added to soln. of tin compd. (1 equiv.) in 1-methyl-2-pyrrolidinone under CO2 at 19°C; GC and NMR monitoring; not isolated;
carbon dioxide; methyl iodide in N,N-dimethyl-formamide; toluene byproducts: CsI; (Ar); standard Schlenk technique; toluene (1 equiv.), MeI (2 equiv.) and CsF (1.4 equiv.) added to soln. of tin compd. (1 equiv.) in DMF under CO2 at 19°C; GC and NMR monitoring; not isolated;
in liquid sulphur dioxide byproducts: Me3SiF; under Ar, anhyd. CsF was suspended in liq. SO2, excess of Me3SiN3 was condensed onto mixt. at -196 °C, mixt. was warmed to room temp.; volatiles were removed at room temp. in dynamic vac., further pumping at50-55 °C for ca. 2 h;
参考文献
Gerken, Michael; Schneider, Stefan; Schroer, Thorsten; Haiges, Ralf; Christe, Karl O.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2002 , vol. 628, # 5 p. 909 - 910
in not given mixt. was shaken for 24 h at room temp.; volatiles were removed;
参考文献
Brooks, Wendell V. F.; MacLean, Gregory K.; Passmore, Jack; White, Peter S.; Wong, Chi-Ming
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983 , p. 1961 - 1968
in hydrogen fluoride HF (liquid); HF condenced onto reagent at 77 K, alowed to warm to room temp., left for 0.5 h, decanted, repeated several times; volatiles removed (vac., ambient temp.);
参考文献
Mazej, Zoran
European Journal of Inorganic Chemistry, 2005 , # 19 p. 3983 - 3987
