in tetrahydrofuran Irradiation (UV/VIS); Stirring of nitroso compound in THF under N2, metal carbonyl in THF is added, the soln. is irradiated for 1 h (sunlamp photolysis) at 30°C.; addn. of naphthalene as internal standard, Gc-anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 368, p. 83 - 102
in neat (no solvent) reaction of cis-bicyclo(4.3.0)nona-3,7-diene with catalytic amt. of Fe(CO)5 at 230°C for 4 h;
参考文献
Kagayama, Takashi; Okabayashi, Shinji; Amaike, Yoichi; Matsukawa, Yasuo; Ishii, Yasutaka; Ogawa, Masaya
Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 7 p. 2297 - 2298
in tetrahydrofuran Stirring of nitroso compound in THF under N2, metal carbonyl in THF is added, the soln. is heated to 65°C for 2 h.; soln. is cooled to 25°C, addn. of biphenyl, GC-anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 368, p. 83 - 102
in tetrahydrofuran Irradiation (UV/VIS); Stirring of nitroso compound in THF under N2, metal carbonyl in THF is added, the soln. is irradiated (sunlamp photolysis) for a period of 1 h.; final purifn. by chromy. on silica gel (dissolving of residue in 19/1 hexane/ethyl acetate);
参考文献
Journal of Organometallic Chemistry, , vol. 368, p. 83 - 102
in xylene refluxed under N2 for 5 h; cooled, filtered, residue washed (acetone), combined filtrates evapd. in vac., chromy. (Al2O3, C6H6 for other product, acetone for this product);
参考文献
Luh, Tien-Yau; Lai, Chi Hung; Tam, Shang Wai
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 444 - 447
acetic acid; acetic anhydride in N,N-dimethyl-formamide N2-atmosphere; filtration of Fe(CO)5 into soln. of HOAc and acetic anhydride, heating to 80°C, then to 115 -120°C 60 h; crystn., filtration, washing (benzene), drying (vac., over H2SO4 and CaCl2); elem. anal.;
参考文献
Catterick, Janet; Thornton, Peter; Fitzsimmons, Brian W.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 1420 - 1425
in N,N-dimethyl-formamide byproducts: CO; Fe(CO)5 was reacted with CH3COOH/(CH3CO)2O in DMF at 140°C; due to Calderazzo, F.; Floriani, C.; Henzi, R.; L'Eplattenier, F. J. Chem. Soc., A, 1969, 1378;
in further solvent(s) byproducts: H2, CH4, C4H10; a suspension of 9-BBN and Fe(CO)5 in nonane was slowly heated to about 140°C (bath temp.) under an inert gas atm.; stirring for about 0.5 h; further products and byproducts; mechanism discussed;; distn. under vac.; mixt. of 9-alkyl-9-BBN obtained, detected by GC/MS; the diboroxane was isolated from distn.-residue by sublimation;;
Ard, Shaun G.; Melko, Joshua J.; Fournier, Joseph A.; Shuman, Nicholas S.; Viggiano, Albert A.
Journal of Physical Chemistry A, 2013 , vol. 117, # 40 p. 10178 - 10185
