in gaseous matrix Irradiation (UV/VIS); Fe(CO)5 in He or Ar slowly flowed though cell; N2O introduced (0.2 mmolmin**-1); UV laser pulses in 298-320 nm region; not isolated, detected by laser-induced fluorescence;
参考文献
Son; Lee; Shin; Ku
Chemical Physics Letters, 2000 , vol. 320, # 5-6 p. 658 - 664
in tetrachloromethane byproducts: CO, H2, nitrogen oxides;
参考文献
Dewar, J.; Jones, H. O.
Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1905 , vol. 76, p. 569 - 569
Full Text Show Details
Gmelin Handbook: Fe: MVol.B2, 88, page 495 - 496
Mond, L.; Langer, C.
Journal of the Chemical Society, 1891 , vol. 59, p. 1092 - 1092
Full Text Show Details
Gmelin Handbook: Fe: MVol.B2, 88, page 495 - 496
1: 4-bromo-benzyl bromide With tetra(n-butyl)ammonium hydrogensulfate; Ca(OH)2 in dichloromethane; water 0.25 h; Inert atmosphere; 2: pentacarbonyliron(0) in dichloromethane; water Inert atmosphere;
参考文献
Crystal Growth and Design, , vol. 10, # 5 p. 2298 - 2305
in tetrahydrofuran Irradiation (UV/VIS); Stirring of nitroso compound in THF under N2, metal carbonyl in THF is added, the soln. is irradiated for 1 h (sunlamp photolysis) at 30°C.; addn. of naphthalene as internal standard, Gc-anal.;
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Journal of Organometallic Chemistry, , vol. 368, p. 83 - 102
in tetrahydrofuran Irradiation (UV/VIS); Stirring of nitroso compound in THF under N2, metal carbonyl in THF is added, the soln. is irradiated (sunlamp photolysis) for a period of 3 h at 30°C.; final purifn. by chromy. on silica gel, elution with 19/1 hexane/ethyl acetate provides a single compound;
参考文献
Journal of Organometallic Chemistry, , vol. 368, p. 83 - 102
iron in gas CO mixing with Fe-compd.; thermal decompn. of Fe-compd. to catalyst; pressures 1-10 atm, temp. 800-1200°C; depending on temp. and pressure;
参考文献
Chemical Physics Letters, , vol. 313, # 1-2 p. 91 - 97
