in hydrogenchloride; diethyl ether shaking Na3PO3S wth HCl in presence of Et2O at ca. -10°C; quick sepn. of organic phase, drying (molecular sieves); obtained as ether soln.;
参考文献
Barieux, Jean-Jacques; Demarcq, Michel C.
Revue de Chimie Minerale, 1984 , vol. 21, p. 611 - 626
in diethyl ether byproducts: KClO4; addn. of 73.6percent HClO4 to a suspension of KH2PO3S in ether;; filtration from KClO4; concg. the acid to 94percent;;
in neat (no solvent) byproducts: H3PO2S2, H3PO4, H3PO3; keeping ground P4S10 in moist air; extn. with ether, not isolated, identification as Na or NH4 salts;
参考文献
Barieux, Jean-Jacques; Demarcq, Michel C.
Revue de Chimie Minerale, 1984 , vol. 21, p. 611 - 626
in neat (no solvent) byproducts: H3PO2S2, H3PO4, H3PO3; keeping ground P4S9 in moist air; extn. with ether; not isolated, identification as Na or NH4 salts;
参考文献
Barieux, Jean-Jacques; Demarcq, Michel C.
Revue de Chimie Minerale, 1984 , vol. 21, p. 611 - 626
