1-(4-溴苯肼)-2-苯乙炔合成路线 （共 49 条）
反应条件
piperidine; silica-supported palladium catalyst
T=70°C; Sonogashira coupling; 0.5 h;
参考文献
Tyrrell, Elizabeth; Whiteman, Leon; Williams, Neil
Synthesis, 2009 , # 5 p. 829 - 835
反应条件
copper(l) iodide; caesium carbonate; Fe(acetylacetonate)3
T=140°C; Sonogashira-Hagihara cross-coupling reaction; 18 h;
参考文献
Rao Volla, Chandra M.; Vogel, Pierre
Tetrahedron Letters, 2008 , vol. 49, # 41 p. 5961 - 5964
反应条件
[Fe(II)(C5H5)(C5H4PPh2)]; gold monoiodide; potassium carbonate in toluene
T=130°C; Sonogashira reaction; 24 h;
参考文献
Li, Pinhua; Wang, Lei; Wang, Min; You, Feng
European Journal of Organic Chemistry, 2008 , # 35 p. 5946 - 5951
反应条件
hydrogenchloride; nitrogen; bis(triphenylphosphine)palladium(II) chloride; copper monoiodide in tetrahydrofuran; 4-bromo-1-iodobenzene
参考文献
Semiconductor Energy Laboratory Co., Ltd.
Patent: US2009/140642 A1, 2009 ;
反应条件
hydrogenchloride; nitrogen; triethylamine; bis(triphenylphosphine)palladium(II) chloride; copper monoiodide in tetrahydrofuran; 4-bromo-1-iodobenzene
参考文献
Kadoma, Hiroshi; Kawakami, Sachiko; Shitagaki, Satoko; Seo, Satoshi
Patent: US2009/184633 A1, 2009 ;
反应条件
triethylamine; bis(triphenylphosphine)palladium(II) chloride in tetrahydrofuran
参考文献
Egawa, Masakazu; Kawakami, Sachiko; Nakashima, Harue; Ohsawa, Nobuharu; Seo, Satoshi; Nomura, Ryoji
Patent: US2007/222374 A1, 2007 ;
反应条件
pyridine; CuCl2·2H2O; triethylamine; p-benozquinone in dichloromethane
T=20°C; 12 h; Schlenk technique;
参考文献
Shi, Leilei; Jia, Wei; Li, Xun; Jiao, Ning
Tetrahedron Letters, 2013 , vol. 54, # 15 p. 1951 - 1955
反应条件
copper(l) iodide; triethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
T=20°C;
参考文献
Grebel-Koehler, Doerthe; Liu, Daojun; De Feyter, Steven; Enkelmann, Volker; Weil, Tanja; Engels, Christiaan; Samyn, Celeste; Muellen, Klaus; De Schryver, Frans C.
Macromolecules, 2003 , vol. 36, # 3 p. 578 - 590
反应条件
tetra-n-butylammonium acetate; [5-Cl-2-{(4-Cl-phenyl)-[(E)-HO-imino]methyl}phenyl-PdCl]2 in 1-methyl-pyrrolidin-2-one
T=110°C; Sonogashira coupling; 7.5 h;
参考文献
Alonso, Diego A.; Najera, Carmen; Pacheco, Ma. Carmen
Advanced Synthesis and Catalysis, 2003 , vol. 345, # 9-10 p. 1146 - 1158
反应条件
oxygen; palladium diacetate in tetrahydrofuran
T=25°C; Sonogashira coupling; P=760.051 Torr; 1.5 h;
参考文献
Pankajakshan, Sreekumar; Loh, Teck-Peng
Chemistry - An Asian Journal, 2011 , vol. 6, # 9 p. 2291 - 2295
