(±)-2-甲基-1-丁醇合成路线 （共 128 条）
反应条件
1: With diborane in dichloromethane T=-16°C; hydroboration; 0.0833333 h; 2: With dihydrogen peroxide in sodium hydroxide Oxidation;
参考文献
Kanth; Brown
Tetrahedron Letters, 2000 , vol. 41, # 49 p. 9361 - 9364
反应条件
hydrogen; [Rh(COD)(DPPB)]BF4 in methanol T=20°C; Reduction; Reductive amination; 20 h;
参考文献
Chemical Communications, , # 19 p. 1867 - 1868
反应条件
sodium hydroxide; formaldehyd; hydroquinone in 1,4-dioxane; ethanol
参考文献
Bayer Aktiengesellschaft
Patent: US4097540 A1, 1978 ;
反应条件
hydrogen; Catalyst C prepared in Example C (nickel on mixed silica-zirconia support Zr:Si:Ni 10:28:1) in water T=280°C; P=10336 Torr; 1 h; Product distribution / selectivity;
参考文献
EP1354881 A1, ;
Page/Page column 6-7 ;
反应条件
hydrogen; Criterion Catalyst 424 (C-424) comprising 3.0-4.5 weight percent nickel on alumina modified with phosphorus (6.0-9.0percent) and molybdenum (16.5-22.5percent) oxides in water T=280 - 300°C; P=10336 - 41329.1 Torr; 1 h; Product distribution / selectivity;
参考文献
EP1354881 A1, ;
Page/Page column 6-7 ;
反应条件
CuO/Cr2O3 T=250°C; P=110326 - 147102 Torr; Hydrogenation;
参考文献
Journal of the American Chemical Society, , vol. 56, p. 689
反应条件
formaldehyd; hydroquinone
参考文献
Bayer Aktiengesellschaft
Patent: US4097540 A1, 1978 ;
反应条件
chromium oxide-copper oxide barium oxide catalyst T=250°C; Hydrogenation.unter Druck;
参考文献
Journal of the American Chemical Society, , vol. 54, p. 4680
Journal of the American Chemical Society, , vol. 54, p. 1146
反应条件
chromium oxide-copper oxide barium oxide catalyst T=250°C; Hydrogenation.unter Druck;
参考文献
Journal of the American Chemical Society, , vol. 54, p. 4680
Journal of the American Chemical Society, , vol. 54, p. 1146
反应条件
hydroxyapatite, Ca/P ratio 1.64 in helium T=100 - 500°C; P=760.051 Torr; Conversion of starting material;
参考文献
EP2080749 A1, ;
Page/Page column 15 ;
