1-苯基癸-1,3-二酮合成路线 （共 42 条）
反应条件
copper(l) iodide; N,N-dimethylaminoacetic acid; [RuCl2Cp*]; caesium carbonate; potassium iodide in N,N-dimethyl-formamide T=120°C; P=760.051 Torr; 24 h; Inert atmosphereSealed tube;
参考文献
Wang, Ping; Rao, Honghua; Zhou, Feng; Li, Chao-Jun; Hua, Ruimao
Journal of the American Chemical Society, 2012 , vol. 134, # 40 p. 16468 - 16471,4
反应条件
potassium carbonate; tetrakis(triphenylphosphine) palladium(0) in water; toluene T=90°C; Suzuki-Miyaura cross-coupling; 0.5 h;
参考文献
Molander, Gary A.; Fumagalli, Tiziano
Journal of Organic Chemistry, 2006 , vol. 71, # 15 p. 5743 - 5747
反应条件
1: diphenyl acetylene With ethylmagnesium bromide; iron(II) chloride in diethyl ether T=20°C; 0.25 h; Inert atmosphere; 2: N,N-dimethyl-formamide in diethyl ether T=20°C; 3.5 h; Inert atmosphere; 3: With hydrogenchloride; water in diethyl ether stereoselective reaction;
参考文献
Ilies, Laurean; Yoshida, Takumi; Nakamura, Eiichi
Journal of the American Chemical Society, 2012 , vol. 134, # 41 p. 16951 - 16954,4
反应条件
(E)-1,2-diphenyl-ethene; hydrogen; dodecacarbonyltetrarhodium(0) in benzene T=60°C; P=152000 Torr; 6 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 61, # 12 p. 4353 - 4360
反应条件
[(P{(C6H11)3})2Pd(Cl)2]; dicobalt octacarbonyl; hydrogen; triethylamine in benzene T=150°C; P=53200 Torr; 1 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 119, # 27 p. 6448 - 6449
反应条件
C34H51NP2; hydrogen; palladium (II) 2,4-pentanedionate; toluene-4-sulfonic acid in tetrahydrofuran T=80°C; P=37503.8 Torr; 20 h; Schlenk techniqueAutoclaveInert atmosphere; Reagent/catalyst; stereoselective reaction;
参考文献
Fang, Xianjie; Zhang, Min; Jackstell, Ralf; Beller, Matthias
Angewandte Chemie - International Edition, 2013 , vol. 52, # 17 p. 4645 - 4649
反应条件
[rhodium(I)(carbonyl)2(acetylacetonate)]; hydrogen; BIPHEPHOS in toluene T=55°C; P=3750.38 Torr; 20 h; Reagent/catalystConcentrationTemperature; stereoselective reaction;
参考文献
Chemical Science, , vol. 4, # 6 p. 2418 - 2422
反应条件
[rhodium(I)(carbonyl)2(acetylacetonate)]; C21H10F12NOP; hydrogen in toluene T=55°C; P=3750.38 Torr; 20 h; stereoselective reaction;
参考文献
Chemical Science, , vol. 4, # 6 p. 2418 - 2422
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in water; toluene T=100°C; 2 h; Schlenk techniqueInert atmosphere;
参考文献
Matsuda, Takanori; Sakurai, Yusuke
European Journal of Organic Chemistry, 2013 , # 20 p. 4219 - 4222
反应条件
RhH(CO)(triphenylphosphine)3; (E)-1,2-diphenyl-ethene; hydrogen; triphenylphosphine in benzene T=80°C; P=20685.9 Torr; 20 h;
参考文献
Australian Journal of Chemistry, , vol. 42, # 4 p. 471 - 478
