1-苯基癸-1,3-二酮合成路线 （共 42 条）
反应条件
1: 31 percent / LDA / tetrahydrofuran / 0.08 h / -78 °C 2: TMSOTf / CH2Cl2 / 5 h / 20 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 66, # 6 p. 2149 - 2153
反应条件
1: 43 percent / 4-MeC6H4SO3H*H2O / 1) 60 deg C, 20 min; 2) room temperature, 1 week 2: 88 percent / 37percent hydrochloric acid / toluene / 0.5 h / Heating View Scheme
参考文献
Journal of Organic Chemistry, , vol. 57, # 18 p. 4925 - 4931
反应条件
1: bromine; triethylamine / dichloromethane / 0 °C / |Schlenk technique; |Inert atmosphere 2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; water / 2 h / 100 °C / |Schlenk technique; |Inert atmosphere View Scheme
参考文献
European Journal of Organic Chemistry, , # 20 p. 4219 - 4222
反应条件
chlorine dioxide in tetrachloromethane
参考文献
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, , vol. 28, p. 847 - 852
反应条件
1: ethanol 2: aq. HCl 3: ion-exchange resin <OH- form> / methanol 4: dimethylsulfoxide View Scheme
参考文献
Justus Liebigs Annalen der Chemie, , p. 1872 - 1875
反应条件
1: ion-exchange resin <OH- form> / methanol 2: dimethylsulfoxide View Scheme
参考文献
Justus Liebigs Annalen der Chemie, , p. 1872 - 1875
反应条件
1.1: sodium ethanolate / ethanol / 1 h / 85 °C / Inert atmosphere 2.1: diisobutylaluminium hydride / hexane; dichloromethane / 3.5 h / -78 - 20 °C 2.2: 0.5 h / 20 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 76, # 23 p. 9678 - 9686
反应条件
tetra-n-butylammonium acetate; palladium diacetate T=90°C; 1 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 15, # 5 p. 1272 - 1279
反应条件
in tetrahydrofuran 1.) reflux, 3 h, 2.) room temperature, overnight;
参考文献
Gupton, John T.; Polaski, Christopher M.
Synthetic Communications, 1981 , vol. 11, # 7 p. 561 - 570
反应条件
[2,2']bipyridinyl; bis(1,5-cyclooctadiene)nickel (0); phosphoric acid 1.) THF, rt, 48 h, 2.) THF; Yield given. Multistep reaction;
参考文献
Tetrahedron, , vol. 54, # 7 p. 1169 - 1184
