1-苯基-1-三甲基甲硅氧基乙烯合成路线 （共 431 条）
反应条件
1: 25 percent / TiCl4 / CH2Cl2 / 1 h / -70 °C
2: tetrahydrofuran / 0.17 h / -50 °C
View Scheme
参考文献
Mulzer, Johann; Bruentrup, Gisela; Hartz, Georg; Kuehl, Uwe; Blaschek, Ursula; Boehrer, Gerald
Chemische Berichte, 1981 , vol. 114, # 11 p. 3701 - 3724
反应条件
1: formaldehyd With chiral water-tolerant In(III)-camphorsulfonate complex in water
T=20°C; Mannich reaction;
2: aniline in water
T=20°C;
3: [(1-phenyl-1-ethenyl)oxy]trimethylsilane in water
T=20°C; 24 h; Further stages.;
参考文献
Xiao, Jian; Loh, Teck-Peng
Synlett, 2007 , # 5 p. 815 - 817
反应条件
in dichloromethane
T=20°C; 12 h;
参考文献
Rudler, Henri; Parlier, Andree; Denneval, Charline; Herson, Patrick
Journal of Fluorine Chemistry, 2010 , vol. 131, # 6 p. 738 - 741
反应条件
(i) Zn-Cu (ii) aq. HCl; Multistep reaction;
参考文献
Imamoto, Tsuneo; Hatajima, Toshihiko; Takiyama, Nobuyuki; Takeyama, Toshiaki; Kamiya, Yasuo; Yoshizawa, Takeshi
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 12 p. 3127 - 3135
反应条件
1: n-BuLi
2: 81 percent / SmI2 / Ambient temperature
View Scheme
参考文献
Imamoto, Tsuneo; Takiyama, Nobuyuki
Tetrahedron Letters, 1987 , vol. 28, # 12 p. 1307 - 1308
反应条件
1.) ether, 0-5 deg C, 3 h, 2.) RT;
参考文献
Moriarty, Robert M.; Prakash, Indra
Synthetic Communications, 1985 , vol. 15, # 7 p. 649 - 656
反应条件
tin(II) trifluoromethanesulfonate; N-(trimethylsilyl)-imidazole in dichloromethane
T=-78 - 0°C;
参考文献
Shimizu, Makoto; Akiyama, Takahiko; Mukaiyama, Teruaki
Chemistry Letters, 1984 , p. 1531 - 1534
反应条件
RhCl(PPh3)3 in 1,4-dioxane
24 h; Heating;
参考文献
Sato, Kazuyuki; Higashinagata, Makoto; Yuki, Takashi; Tarui, Atsushi; Omote, Masaaki; Kumadaki, Itsumaro; Ando, Akira
Journal of Fluorine Chemistry, 2008 , vol. 129, # 1 p. 51 - 55
反应条件
tris(triphenylphosphine)ruthenium(II) chloride in benzene
T=120°C; 7 h;
参考文献
Kamigata, Nobumasa; Udodaira, Kumiko; Shimizu, Toshio
Phosphorus, Sulfur and Silicon and Related Elements, 1997 , vol. 129, p. 155 - 168
反应条件
in dichloromethane
T=20°C; 12 h;
参考文献
Rudler, Henri; Parlier, Andree; Denneval, Charline; Herson, Patrick
Journal of Fluorine Chemistry, 2010 , vol. 131, # 6 p. 738 - 741
