2-(丙烷-2-基)环己酮合成路线 （共 20 条）
反应条件
cerium(III) chloride; sodium iodide in acetonitrile
1.5 h; Heating;
参考文献
Bartoli, Giuseppe; Bosco, Marcella; Dalpozzo, Renato; Giuliani, Arianna; Marcantoni, Enrico; Mecozzi, Tiziana; Sambri, Letizia; Torregiani, Elisabetta
Journal of Organic Chemistry, 2002 , vol. 67, # 25 p. 9111 - 9114
反应条件
tert.-butylhydroperoxide; aluminum oxide in tetrahydrofuran
T=-78°C; 2 h;
参考文献
Nsunda, K. M.; Hevesi, L.
Tetrahedron Letters, 1984 , vol. 25, # 39 p. 4441 - 4444
反应条件
1: (i) LiN(iPr)2, ZnCl2, Et2O, (ii) /BRN= 635680/
2: KHSO4 / nujol
View Scheme
参考文献
Dauben,W.G. et al.
Journal of the American Chemical Society, 1977 , vol. 99, # 10 p. 3414 - 3420
反应条件
1: 84 percent / SnCl4 / CH2Cl2 / 1.5 h / -40 °C
2: 80 percent / tBuOOH, Al2O3 / tetrahydrofuran / 2 h / -78 °C
View Scheme
参考文献
Nsunda, K. M.; Hevesi, L.
Tetrahedron Letters, 1984 , vol. 25, # 39 p. 4441 - 4444
反应条件
sodium hydroxide in water
T=100°C;
参考文献
Yang, Yan-Fang; Shu, Xing-Zhong; Luo, Jian-Yi; Ali, Shaukat; Liang, Yong-Min
Chemistry - A European Journal, 2012 , vol. 18, # 28 p. 8600 - 8604
反应条件
dihydrogen peroxide in tetrahydrofuran
T=0°C; 0.166667 h;
参考文献
Nsunda, K. M.; Hevesi, L.
Tetrahedron Letters, 1984 , vol. 25, # 39 p. 4441 - 4444
反应条件
toluene-4-sulfonic acid in acetone
24 h;
参考文献
Harvey; Miners
Australian Journal of Chemistry, 1979 , vol. 32, # 11 p. 2473 - 2481
反应条件
1: 1.) n-BuLi, 2.) CeCl3 / 1.) THF, hexane, -74 deg C, 30 min, 2a.) -74 deg C, 1 h, 2b.) from -74 deg C to RT, 1.5 h
2: Jones reagent / acetone / 2 h
3: DBU / CH2Cl2; diethyl ether / 3 h
View Scheme
参考文献
Marczak, S.; Wicha, J.
Synthetic Communications, 1990 , vol. 20, # 10 p. 1511 - 1520
反应条件
1: Jones reagent / acetone / 2 h
2: DBU / CH2Cl2; diethyl ether / 3 h
View Scheme
参考文献
Marczak, S.; Wicha, J.
Synthetic Communications, 1990 , vol. 20, # 10 p. 1511 - 1520
参考文献
Conley,R.T.; Nowak,B.E.
Journal of Organic Chemistry, 1962 , vol. 27, p. 3196 - 3201
