in neat (no solvent)
byproducts: NaCl; condensing (FSO2)2NCl at -196°C onto activated NaN3, warming to room temp.; sepn. by low-temp. fractional condensation;
参考文献
Holfter, Hagen; Klapoetke, Thomas M.; Schulz, Axel
Polyhedron, 1996 , vol. 15, # 9 p. 1405 - 1407
in gaseous matrix
Kinetics; byproducts: N2; other Radiation; pyrolysis by CO2-laser pulse; Ar as carrier gas; SF6 as sensitizer; visible spectra collected by a optical multichannel analyzer; UV emission;
参考文献
Benard, D. J.; Chowdhury, M. A.; Winker, B. K.; Seder, T. A.; Michels, H. H.
Journal of Physical Chemistry, 1990 , vol. 94, # 19 p. 7507 - 7514
Seel, F.; Nogradi, J.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1952 , vol. 269, p. 188 - 196
Full Text Show Details
Ashmore, P. G.
Nature (London, United Kingdom), 1953 , vol. 172, p. 449 - 450
in gaseous matrix
Kinetics; in situ prepared N3Cl passed into flow tube (He carrier gas), initial Cl concn. 7.8E+13 to 2.08E+14 cm**-3, 295 K, various molar ratios Cl/N3Cl; mass spectroscopy;
参考文献
Brunning, John; Clyne, Michael A. A.
Chemical Physics Letters, 1984 , vol. 106, p. 337 - 341
