sodium tetrahydroborate
1.) benzene, irradiation; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Russell, Glen A.; Shi, Bing Zhi; Jiang, Wan; Hu, Shuiesheng; Kim, Byeong H.; Baik, Woonphil
Journal of the American Chemical Society, 1995 , vol. 117, # 14 p. 3952 - 3962
1: 1,4-diazabicyclo<2.2.2>octane / Ambient temperature
2: 48percent HBr, conc. H2SO4 / 25 °C
View Scheme
参考文献
Ameer, Farouk; Drewes, Siegfried E.; Emslie, Neville D.; Kaye, Perry T.; Mann, R. Leigh
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2293 - 2295
1: 1,4-diazabicyclo<2.2.2>octane / Ambient temperature
2: 48percent HBr, conc. H2SO4 / 25 °C
View Scheme
参考文献
Ameer, Farouk; Drewes, Siegfried E.; Emslie, Neville D.; Kaye, Perry T.; Mann, R. Leigh
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2293 - 2295
1: 1,4-diaza-bicyclo[2.2.2]octane / neat (no solvent) / 20 °C
2: hydrogen bromide; sulfuric acid / dichloromethane / 0 - 20 °C
View Scheme
参考文献
Ameer, Farouk; Drewes, Siegfried E.; Emslie, Neville D.; Kaye, Perry T.; Mann, R. Leigh
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2293 - 2295
1: 1,4-diazabicyclo<2.2.2>octane / Ambient temperature
2: 73 percent / 48percent HBr, conc. H2SO4 / 25 °C
3: 80 percent Spectr. / NaOC2H5 / ethanol / 3 h
View Scheme
参考文献
Ameer, Farouk; Drewes, Siegfried E.; Emslie, Neville D.; Kaye, Perry T.; Mann, R. Leigh
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2293 - 2295
1: 1,4-diazabicyclo<2.2.2>octane / Ambient temperature
2: 48percent HBr, conc. H2SO4 / 25 °C
3: 85 percent Spectr. / NaOC2H5 / ethanol / 3 h
View Scheme
参考文献
Ameer, Farouk; Drewes, Siegfried E.; Emslie, Neville D.; Kaye, Perry T.; Mann, R. Leigh
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2293 - 2295
1: 1,4-diazabicyclo<2.2.2>octane / Ambient temperature
2: 48percent HBr, conc. H2SO4 / 25 °C
3: 85 percent Spectr. / NaOC2H5 / ethanol / 3 h
View Scheme
参考文献
Ameer, Farouk; Drewes, Siegfried E.; Emslie, Neville D.; Kaye, Perry T.; Mann, R. Leigh
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2293 - 2295
